WANG Yong, WU Qi-jin, LI Qi, et al. Experiment on effects of pre-carbonation duration on the strength of MgO-cured compacted soil[J]. 2026, 47(4): 1160-1170.
DOI:
WANG Yong, WU Qi-jin, LI Qi, et al. Experiment on effects of pre-carbonation duration on the strength of MgO-cured compacted soil[J]. 2026, 47(4): 1160-1170.DOI: 10.16285/j.rsm.2025.0231.
Experiment on effects of pre-carbonation duration on the strength of MgO-cured compacted soil
基于渣土挤压预制桩技术和活性MgO-CO碳化固化法,研究采用MgO替代水泥做固化剂的可行性,探究了预碳化时长对压实土的颗粒级配、质量和含水率、无侧限抗压强度的影响,结合X射线衍射(X-ray diffraction,简称XRD)、热重分析(thermo-gravimetric analysis,简称TGA)、压汞(mercury intrusion porosimetry,简称MIP)和扫描电镜(scanning electron microscopy,简称SEM)试验,对碳化过程产物和微观结构演化特征开展分析,揭示了预碳化时长对MgO固化压实土强度的影响机制。结果表明:预碳化时长1~5 h内,压实土质量随碳化时间先快速增长后趋于平缓,含水率则呈相反趋势;土体不均匀系数C提高,可压实性增强,1~10 m范围的粒组颗粒显著增加;无侧限抗压强度提高先快后缓再趋于稳定,碳化过程生成较高硬度的碳化产物包裹在原始土颗粒表面,提高了颗粒自身的硬度,同时压实过程中碳化产物填充了土体中4~40 m的大孔隙和超大孔隙,此外养护阶段MgO继续水化碳化进一步填充孔隙,提高土体的密实程度,这三者共同作用促进了固化压实土宏观强度的提升;但随着碳化时长增加,碳化产物形成钝化层抑制CO碳化反应的持续进行,同时土中水分不足也阻碍了MgO水化,从而影响碳化阶段的碳化反应,导致固化压实土的强度增长由快向缓转变。
Abstract
Based on the slag extruded precast pile technology and active MgO-CO carbonation curing method
the feasibility of using MgO instead of cement as curing agent was studied. Effects of the pre-carbonation duration on the particle gradation
mass and moisture content
and the unconfined compressive strength of MgO-cured compacted soil were investigated by combining the X-ray diffraction (XRD)
thermo-gravimetric analysis (TGA)
mercury intrusion porosimetry (MIP)
and scanning electron microscopy (SEM) tests. The products of carbonization process and microstructure evolution characteristics were analyzed
and the mechanism of the influence of pre-carbonation duration on the strength of MgO-cured compacted soil was revealed. In pre-carbonation duration of 1−5 h
the mass of compacted soil increases rapidly and then tends to slow down with the carbonization time
but the water content shows in the opposite trend. The coefficient of uniformity C and the compactability increase with the rising number of particles in size of 1−10 m. The unconfined compressive strength increases rapidly then slows down to be stabilized. During the carbonization process
the carbonization products generated by the carbonation process are wrapped around the soil particle surface to improve the hardness. Morever
the carbonization products fill the large to super larger pores (4−40 m) in soil during the compaction
and MgO continues to hydrate and carbonize during the maintenance stage to further fill soil pores
leading to improve the degree of densification. The three mechanisms described above act synergistically to enhance the macroscopic strength of the cured compacted soil. However
with longer pre-carbonation durations
the formation of a passivating layer inhibits further carbonation. In addition
the initial low water content limits MgO hydration
reducing carbonation during the carbonation stage. These factors lead to a transition from rapid to slower strength development in the cured compacted soil.