ZHANG Xing-wen, CAO Jing, LEI Shu-yu, et al. Effect of fulvic acid environment on the structure and permeability
of cement-soil containing humic acid[J]. 2025, 46(S1): 249-261.
DOI:
ZHANG Xing-wen, CAO Jing, LEI Shu-yu, et al. Effect of fulvic acid environment on the structure and permeability
of cement-soil containing humic acid[J]. 2025, 46(S1): 249-261.DOI: 10.16285/j.rsm.2024.1107.
Effect of fulvic acid environment on the structure and permeability
of cement-soil containing humic acid
This study used a fulvic acid (FA) solution with a pH of 6 to simulate the weakly acidic groundwater environment typically caused by humic acid in peat soil. The FA solution soaked soft soil containing humic acid that had been solidified with ordinary Portland cement (OPC). Various methods
including visual observation
microscopic analysis
loss on ignition testing
and osmotic pressure tests
were employed to investigate how this environment influenced the structure and permeability of the humic acid-containing soil-cement. The results indicate that FA undergoes complexation reactions with cement hydration products and polyvalent metal cations released during hydration
leading to the formation of organic metal colloids. This process depletes the hydration products and inhibits further hydration. When the OPC content is low
the quantity of organic metal colloids formed is insufficient
which may cause migration and result in the softening and detachment of the surface soil from the specimens. Additionally
the internal structure of the specimens
influenced by humic acid (HA) and FA
develops granular or blocky interconnected structures with numerous large pores. These changes increase the permeability coefficient (k) of the specimens
with the effect becoming more pronounced with extended immersion. Increasing the OPC content inhibits FA infiltration into the specimen and promotes the deposition of organic metal colloids on the surface
resulting in a dense surface layer. Higher OPC content enhances the bonding of hydration products to soil particles and improves pore filling
increasing the overall integrity. This reduces the number of pores and consequently lowers the k of the specimens. To balance engineering safety with environmental and low-carbon requirements
the OPC content used to solidify humic acid-containing soft soil should be controlled between 23.3% and 30.0%.