WANG Fei, YE Zi-jun, MIAO Wen-quan, et al. The effectiveness and strength characteristics of persulfate-remediated organic-contaminated soil[J]. 2024, 45(12): 3635-3644.
DOI:
WANG Fei, YE Zi-jun, MIAO Wen-quan, et al. The effectiveness and strength characteristics of persulfate-remediated organic-contaminated soil[J]. 2024, 45(12): 3635-3644.DOI: 10.16285/j.rsm.2024.0194.
The effectiveness and strength characteristics of persulfate-remediated organic-contaminated soil
To investigate the efficacy and strength properties of Fe²⁺-activated persulfate remediation for 1
2-dichlorobenzene-contaminated soil with varying persulfate concentrations
we conducted degradation
microscopic
particle size
liquid-plastic limit
unconfined compressive strength (UCS)
and undrained shear tests. The results indicate that adding 15.0% Fe²⁺-activated persulfate achieves a 92.59% removal rate of 1
2-dichlorobenzene. Furthermore
the reaction produces sodium sulfate
calcium sulfate
and ferric hydroxide. Small amounts of sodium sulfate and calcium sulfate fill the pores between soil particles
leading to a denser soil structure. However
the expansive effect of excessive sodium sulfate crystals weakens the inter-particle cohesion
leading to soil loosening. After remediation
the clay content increases
while the silt and sand content decreases. The liquid limit
the plastic capacity and the plastic index increase
while the plastic limit decreases with the increase of the persulfate dosage. The UCS and the maximum shear stress decrease with the increase of the persulfate dosage. The UCS of the soil treated by 10.0% persulfate is 310.75 kPa
20.34% higher than the strength of untreated soil. The maximum deviator stress at shear failure is 142.73 kPa.
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