
哈尔滨工程大学动力与能源工程学院
Published:2025
移动端阅览
席鸿远, 游泰宇, 李戴方哲, et al. 复合氧化还原体系协同脱除船舶柴油机SO2和NO的研究[J]. 2025, (4): 340-348.
席鸿远, 游泰宇, 李戴方哲, et al. 复合氧化还原体系协同脱除船舶柴油机SO2和NO的研究[J]. 2025, (4): 340-348. DOI: 10.16236/j.cnki.nrjxb.202504039.
构建了以海水为溶剂的过硫酸钠(Na
2
S
2
O
8
)/尿素复合氧化还原脱除体系,采用鼓泡反应器,在不同氯离子(Cl
-
)摩尔浓度(0~0.6 mol/L)、碳酸氢根离子(HCO
3
-
)摩尔浓度(0~0.05 mol/L)、反应温度(30~70℃)、Na
2
S
2
O
8
摩尔浓度(0.01~0.20 mol/L)及尿素摩尔浓度(0.1~2.0 mol/L)条件下开展了船舶柴油机脱除SO
2
和NO的试验.结果表明:Cl
-
和HCO
3
-
的存在能够有效强化NO的吸收;反应温度、Na
2
S
2
O
8
摩尔浓度和尿素摩尔浓度的增大均能有效促进NO的脱除;海水及尿素的使用都能降低SO
2
的竞争作用、提升NO脱除效率;NO初始体积分数增加会抑制NO的吸收.尿素的加入能有效抑制溶液中硝酸盐的生成,尿素摩尔浓度为2.0 mol/L时可以使反应后的硝酸盐质量浓度从25.687 mg/L降至15.158 mg/L.Na
2
S
2
O
8
/尿素/海水复合氧化还原脱除体系既有NO脱除的高效性,还能有效解决洗涤废水中硝酸盐含量偏高的问题.
张钊.基于O_3-Na_2SO_3/Urea体系的船舶NO_x和SO_2一体化脱除方法及机理研究[D].哈尔滨工程大学,2022(03).
朱鑫宇.Fe(Ⅱ)EDTA复合吸收液湿法脱硝研究[D].东华理工大学,2021(03).
陈曦,叶丁丁,朱恂,杨扬,兰巧,陈蓉,廖强.尿素/过硫酸钠纸基微流体燃料电池产电特性[J].工程热物理学报,2024(02).
吕立群,李钊,孙文强,刘希瑞,谭建伟,葛蕴珊.柴油机SCR系统快速老化方法研究[J].内燃机学报,2023(06).
杨宁,刘振宇,郝敬洋,吴宇峰,周云龙.鼓泡反应器内碱性溶液的CO_2化学吸收特性研究[J].工程热物理学报,2022(10).
王攀,李凯,李振国,雷利利.Cu源对Cu-SSZ-13催化剂脱除NO_x性能的影响[J].内燃机学报,2022(02).
郭聪慧,李一兵,张娟娟,郝经纬,孙拓,石永,林松,赵旭.氯化亚铁活化过一硫酸盐同步去除氮磷及磷的回收[J].环境工程学报,2020(09).
杨世迎,陈友媛,胥慧真,王萍,刘玉红,王茂东.过硫酸盐活化高级氧化新技术[J].化学进展,2008(09).
杨国华,胡文佳,周江华,胡海刚.船舶尾气臭氧氧化-海水吸收的脱硫脱硝新工艺研究[J].内燃机学报,2008(03).
船用柴油机超低排放控制技术[M].化学工业出版社,2019.
Zhang Zhao,Zhou Song,Xi Hongyuan,Zhou Weijian.Study on removing NO from simulated marine diesel engine exhaust gas using the novel composite system of Ozone-Na2SO3/(NH2)2CO[J].Chemical Engineering Journal,2022.
Shi Feng,Li Kan,Li Juexiu,Ying Diwen,Jia Jinping,Sun Tonghua,Yan Naiqiang,Zhang Xiaojing.Simultaneous wet absorption of SO2 and NOX with mixed Na2SO3 and (NH4)2SO3: Effects of mass concentration ratio and pH[J].Chemical Engineering Journal,2021.
Wang Jianlong,Wang Shizong.Effect of inorganic anions on the performance of advanced oxidation processes for degradation of organic contaminants[J].Chemical Engineering Journal,2021.
College of Power and Energy Engineering, Harbin Engineering University, Harbin 150001, China,College of Power and Energy Engineering, Harbin Engineering University, Harbin 150001, China,College of Power and Energy Engineering, Harbin Engineering University, Harbin 150001, China.A novel method for the synchronous absorption of SO 2 and NO from marine diesel engines[J].Fuel Processing Technology,2020.
Jianlong Wang,Shizong Wang.Reactive species in advanced oxidation processes: Formation, identification and reaction mechanism[J].Chemical Engineering Journal,2020.
Han Mengqi,Jafarikojour Morteza,Mohseni Madjid.The Impact of Chloride and Chlorine Radical on Nitrite Formation during Vacuum UV photolysis of Water[J].Science of The Total Environment,2020.
Zhao Zhang,Song Zhou,Hongyuan Xi,Majed Shreka.A Prospective Method for Absorbing NO2 by the Addition of NaHSO3 to Na2SO3-Based Absorbents for Ship NOx Wet Absorption[J].Energy & Fuels,2020.
Hongyuan Xi,Song Zhou,Zhao Zhang.Novel Method Using Na2S2O8 as an Oxidant to Simultaneously Absorb SO2 and NO from Marine Diesel Engine Exhaust Gases[J].Energy & Fuels,2020.
a National Institute of Clean-and-Low-Carbon Energy , Beijing , People's Republic of China.,b State Key Laboratory of Chemical Engineering, East China University of Science and Technology , Shanghai , People's Republic of China.,a National Institute of Clean-and-Low-Carbon Energy , Beijing , People's Republic of China.,a National Institute of Clean-and-Low-Carbon Energy , Beijing , People's Republic of China.,a National Institute of Clean-and-Low-Carbon Energy , Beijing , People's Republic of China.,b State Key Laboratory of Chemical Engineering, East China University of Science and Technology , Shanghai , People's Republic of China.,a National Institute of Clean-and-Low-Carbon Energy , Beijing , People's Republic of China..Simultaneous removal of SO 2 and NO x from flue gas by wet scrubbing using a urea solution.[J ] .Environmental technology,2019.
Hongyuan Xi,Song Zhou,Jinxi Zhou.New experimental results of NO removal from simulated marine engine exhaust gases by Na 2 S 2 O 8 /urea solutions[J].Chemical Engineering Journal,2019.
Youzhi Ji,Jing Bai,Jinhua Li,Tao Luo,Li Qiao,Qingyi Zeng,Baoxue Zhou.Highly selective transformation of ammonia nitrogen to N 2 based on a novel solar-driven photoelectrocatalytic-chlorine radical reactions system[J].Water Research,2017.
Yang Shaolong,Pan Xinxiang,Han Zhitao,Zhao Dongsheng,Liu Bojun,Zheng Dekang,Yan Zhijun.Kinetics of Nitric Oxide Absorption from Simulated Flue Gas by a Wet UV/Chlorine Advanced Oxidation Process[J].Energy & Fuels,2017.
Zhao Yi,Yuan Bo,Hao Runlong,Tao Zichen.Low-Temperature Conversion of NO in Flue Gas by Vaporized H2O2 and Nanoscale Zerovalent Iron[J].Energy & Fuels,2017.
Parmila Devi,Umashankar Das,Ajay K. Dalai.In-situ chemical oxidation: Principle and applications of peroxide and persulfate treatments in wastewater systems[J].Science of The Total Environment,2016.
Yusuf G. Adewuyi,Nana Y. Sakyi.Simultaneous Absorption and Oxidation of Nitric Oxide and Sulfur Dioxide by Aqueous Solutions of Sodium Persulfate Activated by Temperature[J].Industrial & Engineering Chemistry Research,2013.
Ping Fang,Chaoping Cen,Zhixiong Tang,Peiyi Zhong,Dingsheng Chen,Zhihang Chen.Simultaneous removal of SO 2 and NO X by wet scrubbing using urea solution[J].Chemical Engineering Journal,2010.
Nymul E. Khan,Yusuf G. Adewuyi.Absorption and Oxidation of Nitric Oxide (NO) by Aqueous Solutions of Sodium Persulfate in a Bubble Column Reactor[J].Industrial & Engineering Chemistry Research,2010.
P. Neta,Robert E. Huie,Alberta B. Ross.Rate Constants for Reactions of Inorganic Radicals in Aqueous Solution[J].Journal of Physical and Chemical Reference Data,2009.
Jinchao Wei,Yunbai Luo,Ping Yu,Bo Cai,Houzhang Tan.Removal of NO from flue gas by wet scrubbing with NaClO 2 /(NH 2 ) 2 CO solutions[J].Journal of Industrial and Engineering Chemistry,2008.
Buxton GV.,Salmon GA.,Williams JE.,Bydder M..The reactivity of chlorine atoms in aqueous solution. Part III. The reactions of Cl-center dot with solutes[J].Physical chemistry chemical physics: PCCP,2000.
0
Views
7
下载量
0
CSCD
Publicity Resources
Related Articles
Related Author
Related Institution
京公网安备11010802024621