Research Progress of Heterojunction Photocatalysts

许西威; 陈小平

doi:10.16056/j.2096-7705.2022.04.013

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Research Progress of Heterojunction Photocatalysts

更新时间：2026-01-19

- Research Progress of Heterojunction Photocatalysts
- Issue 4, Pages: 78-84(2022)
- 作者机构：
  
  1. 江西省科学院能源研究所
  2. 江西省碳中和研究中心 3. 江西省碳中和技术创新中心
- 作者简介：
- 基金信息：
- DOI：10.16056/j.2096-7705.2022.04.013
  CLC： X703;O644.1;O643.36
- Published：2022
- 稿件说明：
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许西威, 陈小平. Research Progress of Heterojunction Photocatalysts[J]. 2022, (4): 78-84.
DOI：

许西威, 陈小平. Research Progress of Heterojunction Photocatalysts[J]. 2022, (4): 78-84. DOI： 10.16056/j.2096-7705.2022.04.013.

摘要

光催化氧化技术具有合成过程简便、反应条件易控制、充分利用太阳能且无二次污染等其他水处理技术无可比拟的优点，在处理环境污染问题和缓解全球能源短缺等方面的应用前景越来越广阔。但大多数光催化剂会面临光生载流子快速复合、可见光吸收范围窄、低效的氧化还原能力等方面的限制。因此，研究人员对光催化剂进行了诸多方面的改性，其中，多个半导体耦合形成异质结是提高光生载流子分离效率以及光催化活性的有效手段。在此，论述了国内外异质结型光催化剂的研究进展，重点分析了Ⅱ型、传统Z型、全固态Z型、直接Z型、S型这几种具有代表性的异质结光催化剂，对其各自特点、作用原理以及局限性进行讨论。并提出未来新型S型异质结可通过调整RP和OP的费米能级、助催化剂修饰、形态工程与界面调节等手段进一步提高光催化性能和拓宽应用范围。

Abstract

Photocatalytic oxidation technology has incomparable advantages over other water treatment technologies

such as simple synthesis process

easy control of reaction conditions

full use of clean energy and solar energy

and no secondary pollution. It has an increasingly broad application prospect in dealing with environmental pollution and alleviating global energy shortage. However

most photocatalysts are limited by the rapid recombination of photogenerated carriers

narrow visible light absorption range

and inefficient redox ability. Therefore

researchers have modified photocatalysts in many aspects. Among them

the coupling of multiple semiconductors to form heterojunctions is an effective means to improve the separation efficiency of photogenerated carriers and the photocatalytic activity. In this paper

the research progress of heterojunction photocatalysts at home and abroad is reviewed

focusing on the analysis of several representative heterojunction photocatalysts: Ⅱ-scheme

traditional Z-scheme

all-solid-state Z-scheme

direct Z-scheme

and S-scheme

and their respective characteristics

principles of action

and limitations are discussed. In the future

the new S-scheme heterojunction can further improve the photocatalytic performance and broaden the application range by adjusting the Fermi level of RP and OP

cocatalyst modification

morphological engineering and interface regulation.

关键词

Keywords

references

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