Rational Design and Fabrication of CeO<sub>2</sub>@FeOOH Hetrotructure as Anodic Electrocatalyst for Water Splitting

黎建刚; 徐凯; 黄振雄; 詹聪; 邓同辉; 李琴; 陈泊宏

doi:10.16056/j.2096-7705.2022.01.007

English Version Reader LoginJournal Login

您当前的位置：

首页 >

文章列表页 >

Rational Design and Fabrication of CeO₂@FeOOH Hetrotructure as Anodic Electrocatalyst for Water Splitting

更新时间：2026-01-19

- Rational Design and Fabrication of CeO₂@FeOOH Hetrotructure as Anodic Electrocatalyst for Water Splitting
- Issue 1, Pages: 41-48(2022)
- 作者机构：
  
  1. 江西省科学院能源研究所
  2. 江西省碳中和研究中心 3. 江西省碳中和技术创新中心
  3. 武汉船用电力推进装置研究所
- 作者简介：
- 基金信息：
- DOI：10.16056/j.2096-7705.2022.01.007
  CLC： TQ116.21;TQ426
- Published：2022
- 稿件说明：
移动端阅览
黎建刚, 徐凯, 黄振雄, et al. Rational Design and Fabrication of CeO₂@FeOOH Hetrotructure as Anodic Electrocatalyst for Water Splitting[J]. 2022, (1): 41-48.
DOI：

黎建刚, 徐凯, 黄振雄, et al. Rational Design and Fabrication of CeO₂@FeOOH Hetrotructure as Anodic Electrocatalyst for Water Splitting[J]. 2022, (1): 41-48. DOI： 10.16056/j.2096-7705.2022.01.007.

摘要

为开发出一种高效且低能耗的电解水制氢催化剂，引入界面工程调控手段，构筑了包含CeO

和FeOOH界面结构的纳米复合材料CeO

@FeOOH。首先通过一步水热法制备了CeO

纳米结构，随后以其为基底材料，采用水浴法，以FeSO

·7H

O作为铁源，Fe

水解并被氧化最终于CeO

表面形成FeOOH结构。材料的微观形貌及其物相结构表征证实，所得复合材料为无定型结构的纳米颗粒，且负载的FeOOH表现为无特定晶型结构。电化学测试结果表明，所得材料CeO

@FeOOH具有碱性电解水阳极端催化活性，当驱动电流密度为10 m A/cm

时，其所需过电势为292 m V，相较于其构筑界面前的单体材料CeO

(335 mV)和FeOOH (340 mV)分别提升12.8%和14.1%。结果表明：通过构筑CeO

和FeOOH界面结构，能够有效提升复合材料的碱性电解水催化活性，且所得材料CeO

@FeOOH相较于商用催化剂具有低成本、长周期稳定性以及高催化活性的竞争优势。

Abstract

In order to develop a high-efficiency and low-energy-consumption catalyst for water to hydrogen electrolysis production

the interface engineering method was introduced to construct a nanocomposite material CeO

@FeOOH which containing the interface structure of CeO

and FeOOH.First

the CeO

nanostructure was prepared by a one-step hydrothermal method

and

which then serving as the base material.By using the FeSO

·7H

O as the iron source under the water bath treating

ion was hydrolyzed and oxidized to form FeOOH structure on the surface of CeO

.The microscopic morphology of the material and the phase structure characterization confirmed that the obtained composite material was the amorphous structure of nano-particles

and the loaded FeOOH exhibits an amorphous crystal structure.The electrochemical test results show that the obtained material CeO

@FeOOH has the good performance of catalytic activity toward the anodic of alkaline electrolyzed water.When it driving the current density of 10 m A/cm~2

the required overpotential is 292 mV

which better than The results show that by constructing the CeO

and FeOOH interface structure

the catalytic activity of alkaline electrolysis water of the composite material can be effectively improved

and the obtained material CeO

@FeOOH owns the competitive advantages of low cost

long-term stability and high catalytic activity compared with that of commercial catalysts.

关键词

Keywords

references

V掺杂Co_4N的双功能型电解水催化剂的设计与制备[J]. 黎建刚;黄振雄;詹聪;邓同辉;李琴;席细平.能源研究与管理,2021(03)

二氧化铈纳米结构的制备方法研究进展[J]. 唐红梅;李琴;黄振雄;邓同辉;詹聪;黎建刚.能源研究与管理,2021(03)

Synergistic Coupling of NiTe Nanoarrays with FeOOH Nanosheets for Highly Efficient Oxygen Evolution Reaction[J]. Yadong Li;Baojin Chen;Huaming Zhang;Jing Gao;Huachuan Sun;Aziz Habibi-Yangjeh;Chundong Wang.ChemElectroChem,2021(19)

Oxygen Reduction Electrocatalysts toward Practical Fuel Cells: Progress and Perspectives.[J]. Zaman Shahid;Huang Lei;Douka Abdoulkader Ibro;Yang Huan;You Bo;Xia Bao Yu.Angewandte Chemie (International ed. in English),2021

Engineering the coupling interface of rhombic dodecahedral NiCoP/C@FeOOH nanocages toward enhanced water oxidation.[J]. Li JianGang;Gu Yu;Sun Huachuan;Lv Lin;Li Zhishan;Ao Xiang;Xue Xinying;Hong Guo;Wang Chundong.Nanoscale,2019(42)

Recent Progress in Decoupled H 2 and O 2 Production from Electrolytic Water Splitting[J ] . Xuan Liu;Jingqi Chi;Prof. Bin Dong;Prof. Yujie Sun.ChemElectroChem,2019(8)

Metal-Organic Framework-Derived Hierarchical (Co, Ni)Se2@NiFe LDH Hollow Nanocages for Enhanced Oxygen Evolution.[J]. Li Jian-Gang;Sun Huachuan;Lv Lin;Li Zhishan;Ao Xiang;Xu Chenhui;Li Yi;Wang Chundong.ACS applied materials & interfaces,2019(8)

Liquid Exfoliated Co(OH) 2 Nanosheets as Low‐Cost, Yet High‐Performance, Catalysts for the Oxygen Evolution Reaction[J ] . David McAteer;Ian J. Godwin;Zheng Ling;Andrew Harvey;Lily He;Conor S. Boland;Victor Vega‐Mayoral;Beata Szyd?owska;Aurélie A. Rovetta;Claudia Backes;John B. Boland;Xin Chen;Michael E. G. Lyons;Jonathan N. Coleman.Advanced Energy Materials,2018(15)

Improved Electrocatalytic Performance of Core-shell NiCo/NiCoO x with amorphous FeOOH for Oxygen-evolution Reaction[J]. Yubo Shao;Meiyong Zheng;Minmin Cai;Lan He;Cailing Xu.Electrochimica Acta,2017

Design and Synthesis of FeOOH/CeO2 Heterolayered Nanotube Electrocatalysts for the Oxygen Evolution Reaction.[J]. Feng Jin-Xian;Ye Sheng-Hua;Xu Han;Tong Ye-Xiang;Li Gao-Ren.Advanced materials (Deerfield Beach, Fla.),2016(23)

Advances on methane steam reforming to produce hydrogen through membrane reactors technology: A review[J]. Adolfo Iulianelli;Simona Liguori;Jennifer Wilcox;Angelo Basile.Catalysis Reviews,2016(1)

Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions.[J]. Jiao Yan;Zheng Yao;Jaroniec Mietek;Qiao Shi Zhang.Chemical Society reviews,2015(8)

A Janus cobalt-based catalytic material for electro-splitting of water.[J]. Cobo Saioa;Heidkamp Jonathan;Jacques Pierre-André;Fize Jennifer;Fourmond Vincent;Guetaz Laure;Jousselme Bruno;Ivanova Valentina;Dau Holger;Palacin Serge;Fontecave Marc;Artero Vincent.Nature materials,2012(9)

Synthesis of Fe-doped CeO 2 nanorods by a widely applicable coprecipitation route[J]. Zizi Wang;Ying Xin;Zhaoliang Zhang;Qian Li;Yihe Zhang;Limin Zhou.Chemical Engineering Journal,2011

Recent progress in alkaline water electrolysis for hydrogen production and applications[J]. Kai Zeng;Dongke Zhang.Progress in Energy and Combustion Science,2009(3)

Ionic Dispersion of Pt over CeO2 by the Combustion Method:? Structural Investigation by XRD, TEM, XPS, and EXAFS[J]. Bera Parthasarathi;Priolkar K. R.;Gayen Arup;Sarode P. R.;Hegde M. S.;Emura S.;Kumashiro R.;Jayaram V.;Subbanna G. N..Chem. Mater.,2003(10)

Views

243

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

No data

Related Author

No data

Related Institution

No data

AI问答

⁰

Rational Design and Fabrication of CeO2@FeOOH Hetrotructure as Anodic Electrocatalyst for Water Splitting

DOI：10.16056/j.2096-7705.2022.01.007

摘要

Abstract

关键词

Keywords

references

Rational Design and Fabrication of CeO₂@FeOOH Hetrotructure as Anodic Electrocatalyst for Water Splitting