江西省科学院能源研究所
Published:2021
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唐红梅, 李琴, 黄振雄, et al. Fabricate Methodology Research Progress of CeO2 with Nanostructures[J]. 2021, (3): 18-26.
DOI:
唐红梅, 李琴, 黄振雄, et al. Fabricate Methodology Research Progress of CeO2 with Nanostructures[J]. 2021, (3): 18-26. DOI: 10.16056/j.2096-7705.2021.03.005.
CeO
2
纳米结构具有表面效应、体积效应、量子尺寸效应和宏观隧道效应
表现出独特的理化性质
并在精密陶瓷、磁记录、紫外线屏蔽、光电传感以及催化等领域得到广泛应用。对CeO
纳米结构的制备方法进行总结归纳
不仅为开发新型结构CeO
提供科学指导
也进一步促进纳米CeO
在相关领域的高效利用。在此
论述了国内外CeO
纳米结构制备技术的研究现状
重点分析了燃烧法、喷雾热分解法、超临界水体系氧化法、微波法、溶胶-凝胶法、微乳液法、电化学法以及水/溶剂热法
并对其特点、原理以及局限性进行了说明。研究表明
纳米结构的可控制备仍是现阶段面临的难题
此外
材料制备中所涉及的热力学和反应动力学等模型还有待完善。因此
需深入对其制备过程中涉及的相关基础理论进行研究
明确其成核与生长机制
为CeO
新型纳米结构的开发和应用提供参考。
Nano-structured CeO
with the characters of surface effects
volume effects
quantum size effects and macro-tunneling effects
exhibiting the unique physical and chemical properties
which have been widely used in the fields of precision ceramics
magnetic recording
ultraviolet shielding
photoelectric sensing and catalysis. To summary of the preparation methods of CeO
nanostructures will not only provides the scientific guidance for the development of novel nano-structures of CeO
but also further promotes the efficient use of
nano-CeO
in related fields. Here
the research status of the fabrication methodology of nano-CeO
were discussed
the including of combustion method
spray thermal decomposition method
supercritical water system oxidation method
microwave method
sol-gel method
microemulsion method
electrochemical method and hydrothermal/solvothermal method were analyzed. The involved characteristics
principles and limitations also been explained. As result
the research found that the controllable preparation of CeO
nanostructures is still a difficult problem at this stage. In addition
the thermodynamics and reaction kinetics models involved during the preparation have yet to be improved. Therefore
it is necessary to focus on the in-depth research in the relevant basic theories on the preparation process
the mechanism of nucleation and growth should be clarified in detail
which in turn to provide a reference for the development of novel nano-CeO
.
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