姚萌, 方永珍, 兰秀娟, et al. Reverse Osmosis Membrane Fouling Cleaning in Recycling Technology of Coking Wastewater[J]. 2021, (1): 100-103+127. DOI: 10.16056/j.2096-7705.2021.01.019.
Reverse Osmosis Membrane Fouling Cleaning in Recycling Technology of Coking Wastewater
摘要
采用双膜法工艺处理焦化废水
实现中水回用。项目选用型号DOW
TM
BW30XFR-400/34i卷式反渗透膜
初始运行通量16 LMH
经过6月运行后
通量下降>95%。膜元件采用浸泡方式能极大程度地提高清洗效果
采用LC-07强酸型清洗剂对膜通量恢复和截留率的提升效果显著
膜元件截留率可以由清洗前的57.23%稳定恢复至>90%。SEM结果显示
清洗后膜表面仍然残留有少量的污染物
ATR-FTIR谱图显示经化学清洗后
聚砜支撑层的O=S=O对称伸缩振动峰发生明显红移
酰胺I和酰胺II特征峰整体发生蓝移
可能是膜面污染物的存在导致特征基团的电子跃迁。
Abstract
Double-membrane process was used for coking wastewater reuse
the DOW
TM
BW30XFR-400/34 i series reverse osmosis membrane was selected in the project. In comparison with new BW30 XFR membrane module
the flux decreased more than 95% for the fouled membrane module. It was found that the recovery of membrane capability required repeated and long-term chemical cleaning. The soaking method could improve the cleaning effect greatly. LC-07 could remarkable effect on membrane characteristics with more than 95% flux recovery. The rejection of membrane increases to more than 90% after chemical cleaning
contrast with 57.23% of fouled membrane. As shown in SEM results
there were still membrane foulants on the
membrane surface. ATR-FTIR spectra showed that after chemical cleaning
the O=S=O symmetrical stretching vibration peak of the support layer of polysulfone had obvious red shift
and the characteristic peaks of amide I and amide II had blue shift
which might be that the presence of pollutants in the membrane surface led to the electronic transition of the characteristic groups.