姜钦亮, 麦兆环, 桂双林, et al. Effects of Mixed Additives on the Structure and Performance of PMIA Flat Sheet Ultrafiltration Membrane[J]. 2020, (3): 23-28+43. DOI: 10.16056/j.2096-7705.2020.03.006.
Effects of Mixed Additives on the Structure and Performance of PMIA Flat Sheet Ultrafiltration Membrane
摘要
为考察混合添加剂对聚间苯二甲酰间苯二胺(PMIA)平板超滤膜结构和性能的影响
在以N
N二甲基乙酰胺(DMAc)为溶剂
氯化锂(Li Cl)和聚乙二醇400 (PEG400)为混合添加剂的条件下
制备了PMIA/无纺布平板超滤膜
进行了混合添加剂配比对铸膜液黏度、膜的形貌结构及分离性能的影响分析。结果表明
当Li Cl与PEG400的质量分数配比由5∶0上升至优化配比为5∶2时
膜表面形貌主要表现在膜孔变小
膜表面变得更加致密。超滤实验结果表明
Li Cl和PEG400质量分数比为5∶2的条件下制备的PMIA平板超滤膜具有2 692 L/(m2·h·MPa)的纯水通量及96.5%的BSA截留率。PMIA膜在100 mg/L HA溶液超滤运行6.0 h通量基本稳定
研究表明膜具有良好的抗污染性能。
Abstract
Poly(m-phenylene isophthalamide)(PMIA) flat sheet ultrafiltration membrane based on the support of nonwoven fabric were fabricated under the condition of using DMAc as solvent
lithium chloride and PEG400 as mixed additives
and the influence of PEG400 and Li Cl content on the structure and performance of the membranes were investigated. Effect of mixed additives content on the viscosity of the casting solution
the morphology and the characteristics of the resulted membranes were investigated in detail. The results showed that when the ratio of Li Cl to PEG400 increased from 5 ∶0 to 5∶2
the membrane surface morphology mainly showed that the membrane pores became smaller and the membrane surface became more compact. The lowest contact angle of the prepared membrane water was 46.7°
indicating good hydrophilicity.The results of ultrafiltration experiment showed that the PMIA flat sheet ultrafiltration membrane prepared under the condition of 5∶2 mass fraction ratio between Li Cl and PEG400 had the pure water flux of 2 692 L/(m2·h·MPa) and the BSA retention rate of 96.5%. The flux of PMIA membrane remained stable after 6 h ultrafiltration operation of 100 mg/L HA solution
and the study showed that the membrane had good anti-pollution performance.