梁大镁, 安城, 刘晶. Effect of WFGD Parameters on Element Mercury Removal Efficiency[J]. 2018, (3): 39-43. DOI: 10.16056/j.1005-7676.2018.03.011.
Effect of WFGD Parameters on Element Mercury Removal Efficiency
摘要
湿法脱硫系统在除去SO
2
的同时也能脱除单质汞
但脱硫参数对单质汞脱除效率的影响较大。为了研究湿法脱硫的各个参数对于单质汞脱除效率的影响
在实验室条件下模拟湿法脱硫过程。主要考察了温度、O2浓度、SO
2
体积分数、pH值、脱硫液浓度和卤素离子(Cl
-
、Br
-
、I
-
)浓度对于单质汞脱除效率的影响。结果表明湿法脱硫对单质汞的最佳脱除温度在55℃左右。Hg
0
的脱除效率随p H值、O2浓度和脱硫液浓度的增加而增加
而SO
2
浓度的增加对Hg
0
的脱除有抑制作用。Cl
-
、Br
-
、I
-
都能促进Hg
0
的氧化脱除
促进顺序为Br
-
>I
-
>Cl
-
。
Abstract
The wet flue gas desulfurization(WFGD) can remove the elemental mercury when removing SO
2
but the parameters have a great influence on the mercury removal efficiency. To study the effect of various parameters of WFGD on the elemental mercury removal efficiency
the wet desulfurization process was simulated under laboratory conditions. The effects of temperature
O2 concentration
SO
2
concentration
p H value
slurry concentration and halogen ion(Cl
-
Br
-
I
-
)concentration on the elemental mercury removal efficiency were investigated.
The experiment results show that the best reaction temperature is 55 ℃. The mercury removal efficiency increases with the increase of pH value
O
2
concentration and slurry concentration
but SO
2
shows resistance performance for mercury removal with the increase of SO