Research of Key Technologies for n-i-p Perovskite Solar Cells With SnO<sub>2</sub> Electron Transport Layer

YUE Xiaopeng; ZHAO Xing; YAN Huilin; FAN Bingbing; HUANG Hao; YAN Luyao; CUI Peng; MA Junfeng; LI Meicheng

doi:10.12096/j.2096-4528.pgt.22072

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Research of Key Technologies for n-i-p Perovskite Solar Cells With SnO₂ Electron Transport Layer

New Energy | 更新时间：2025-06-06

- Research of Key Technologies for n-i-p Perovskite Solar Cells With SnO₂ Electron Transport Layer
- Power Generation Technology Vol. 44, Issue 1, Pages: 63-77(2023)
- 作者机构：
  
  1.华北电力大学新能源学院,北京市昌平区 102206
  2.河北工程大学能源与环境工程学院,河北省邯郸市 056038
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China(51972110;52102245;52072121);Beijing Natural Science Foundation(2222076;2222077);Independent Subject of State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources(LAPS202114);Science and Technology Projects of China Huaneng Group Co., Ltd(HNKJ20-H88);Fundamental Research Funds for the Central Universities(2020MS023;2020MS028);Double First-class Construction Project of North China Electric Power University
- DOI：10.12096/j.2096-4528.pgt.22072
  CLC： TK 01
- Received：07 April 2022，
  
  Published：28 February 2023
- 稿件说明：
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岳晓鹏,赵兴,闫慧琳等.基于SnO₂电子传输层的n-i-p型钙钛矿太阳能电池关键技术研究[J].发电技术,2023,44(01):63-77.

YUE Xiaopeng,ZHAO Xing,YAN Huilin,et al.Research of Key Technologies for n-i-p Perovskite Solar Cells With SnO₂ Electron Transport Layer[J].Power Generation Technology,2023,44(01):63-77.
岳晓鹏,赵兴,闫慧琳等.基于SnO₂电子传输层的n-i-p型钙钛矿太阳能电池关键技术研究[J].发电技术,2023,44(01):63-77. DOI： 10.12096/j.2096-4528.pgt.22072.

YUE Xiaopeng,ZHAO Xing,YAN Huilin,et al.Research of Key Technologies for n-i-p Perovskite Solar Cells With SnO₂ Electron Transport Layer[J].Power Generation Technology,2023,44(01):63-77. DOI： 10.12096/j.2096-4528.pgt.22072.

摘要

钙钛矿太阳能电池(perovskite solar cells，PSCs)由于光电转换效率高、制备工艺简单、成本低等优势受到广泛关注，电池效率已从3.8%提升到25.7%。目前，对基于SnO

电子传输层的n-i-p型平板结构电池的研究越来越多，但存在着工艺可重复性差、效率低等问题。针对n-i-p型平板结构PSCs的制备进行了系统的研究，包括导电基底的选择、钙钛矿制备工艺参数的优化以及电池存储环境。结果证明，上述参数对于电池均具有重要影响，并结合扫描电子显微镜、X射线衍射、吸收光谱分析了原因。在最优工艺条件下(掺锡氧化铟基底，PbI

退火温度70 ℃(1 min)，胺盐溶液滴加后静置时间不超过5 s，存储湿度4.5%)，器件平均效率达到21.85%，最高效率达到23.47%，迟滞可忽略，具有良好的可重复性。研究结果可为制备重复性好、光电转换效率高的PSCs提供科学支撑。

Abstract

Perovskite solar cells (PSCs) have attracted extensive attentions due to their high-efficiency

simple preparation process and low-cost. The efficiency of the PSCs has increased from 3.8% to 25.7%. So far

more and more studies focus on n-i-p structured PSCs using SnO

as electron tra

nsport layer. However

its process reproducibility is relatively poor

and efficiency is still low. This report conducted a systematic study of planar n-i-p PSCs

mainly including the selection of transparent conductive oxide (TCO) glass

optimization of preparation parameters and the influence of storage conditions on device performance. Experimental results show that these parameters have an important impact on the device performance. At the same time

it was analyzed by scanning electron microscope

X-ray diffraction

absorption spectrum. The devices achieved an average efficiency of 21.85% and a highest efficiency of 23.47% with good reproducibility under the optimal conditions (Indium Tin oxide substrate

PbI

annealed at 70 ℃ for 1 min

standing time after dropping amine salt solution is less than 5 s

and stored in 4.5% humidity environment). This work provides scientific support for the preparation of high-efficiency and repeatable PSCs.

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Research of Key Technologies for n-i-p Perovskite Solar Cells With SnO2 Electron Transport Layer

DOI：10.12096/j.2096-4528.pgt.22072

摘要

Abstract

关键词

Keywords

references

Research of Key Technologies for n-i-p Perovskite Solar Cells With SnO₂ Electron Transport Layer