Research Progress of Solid-Gas Two-Phase Chemical Heat Storage Technology for Solar Thermal Power Generation

Zezhong WANG; Pingrui HUANG; Gaosheng WEI; Liu CUI; Chao XU; Xiaoze DU

doi:10.12096/j.2096-4528.pgt.21014

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Research Progress of Solid-Gas Two-Phase Chemical Heat Storage Technology for Solar Thermal Power Generation

New and Renewable Energy | 更新时间：2025-07-04

- Research Progress of Solid-Gas Two-Phase Chemical Heat Storage Technology for Solar Thermal Power Generation
- Power Generation Technology Vol. 42, Issue 2, Pages: 238-246(2021)
- 作者机构：
  
  电站能量传递转化与系统教育部重点实验室(华北电力大学), 北京市昌平区 102206
- 作者简介：
- 基金信息：
  
  National Key Research & Development Plan of China(2017YFB061804)
- DOI：10.12096/j.2096-4528.pgt.21014
  CLC： TK11
- Received：04 March 2021，
  
  Published：30 April 2021
- 稿件说明：
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Zezhong WANG, Pingrui HUANG, Gaosheng WEI, et al. Research Progress of Solid-Gas Two-Phase Chemical Heat Storage Technology for Solar Thermal Power Generation[J]. Power Generation Technology, 2021, 42(2): 238-246.
DOI：

Zezhong WANG, Pingrui HUANG, Gaosheng WEI, et al. Research Progress of Solid-Gas Two-Phase Chemical Heat Storage Technology for Solar Thermal Power Generation[J]. Power Generation Technology, 2021, 42(2): 238-246. DOI： 10.12096/j.2096-4528.pgt.21014.

摘要

化学储热作为一种储热密度高、存储时间长、运输距离远的储热方式，近些年来得到广泛研究。首先针对现存的几类固–气两相化学储热反应体系的基本原理和研究进展进行了综述，主要涉及金属氢氧化物反应体系、金属氧化物反应体系、碳酸盐反应体系以及水合盐反应体系。然后依据固相反应物在反应器内的运动状态，将反应器分为固定床反应器、流化床反应器和移动床反应器3类，并分别对其研究进展进行了总结。最后基于目前在化学储热研究中存在的一些不足，分析了化学储热未来的发展趋势。目前，化学储热充/放热过程的有效控制仍需进一步研究，化学反应速率与传热的强化与匹配也还存在技术困难。长期运行状况下，化学储热的循环稳定性仍有待进一步探究。

Abstract

As a heat storage method with high heat storage density

long storage time and long transportation distance

the chemical heat storage has been widely studied in recent years. This article firstly summarized the basic principles and research progress of several existing solid-gas two-phase chemical heat storage reaction systems

mainly involving the metal hydroxide reaction

metal oxide reaction

carbonate reaction

and hydration salt reaction. Then

according to the moving state of solid phase reactant in the reactor

the reactor was divided into three types: the fixed bed reactor

fluidized bed reactor and moving bed reactor. Moreover

their research progress was summarized respectively. Finally

based on the current deficiencies in the research of chemical heat storage

the future development trend of chemical heat storage was analyzed. At present

the storage still needs further research

and there are still technical difficulties in strengthening and matching the chemical reaction rate and heat transfer. The cyclic stability of chemical heat storage under long-term operation condition still needs to be further explored.

关键词

Keywords

references

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