Process Modelling and Thermodynamic Analysis of Hydrogen Production by High Temperature Solid Oxide Electrolysis Under the Background of Carbon Neutrality

Dandan WANG; Yalou LI; Fang LI; Lu SUN

doi:10.12096/j.2096-4528.pgt.21010

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Process Modelling and Thermodynamic Analysis of Hydrogen Production by High Temperature Solid Oxide Electrolysis Under the Background of Carbon Neutrality

Carbon Neutrality | 更新时间：2025-07-04

- Process Modelling and Thermodynamic Analysis of Hydrogen Production by High Temperature Solid Oxide Electrolysis Under the Background of Carbon Neutrality
- Power Generation Technology Vol. 42, Issue 5, Pages: 554-560(2021)
- 作者机构：
  
  电网安全与节能国家重点实验室(中国电力科学研究院有限公司), 北京市海淀区 100192
- 作者简介：
- 基金信息：
  
  National Key Research and Development Program of China(2018YFE0208400);Project of China Electric Power Research Institute(5242002000RF)
- DOI：10.12096/j.2096-4528.pgt.21010
  CLC： TK91;TQ116.2
- Received：18 February 2021，
  
  Published：31 October 2021
- 稿件说明：
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Dandan WANG, Yalou LI, Fang LI, et al. Process Modelling and Thermodynamic Analysis of Hydrogen Production by High Temperature Solid Oxide Electrolysis Under the Background of Carbon Neutrality[J]. Power Generation Technology, 2021, 42(5): 554-560.
DOI：

Dandan WANG, Yalou LI, Fang LI, et al. Process Modelling and Thermodynamic Analysis of Hydrogen Production by High Temperature Solid Oxide Electrolysis Under the Background of Carbon Neutrality[J]. Power Generation Technology, 2021, 42(5): 554-560. DOI： 10.12096/j.2096-4528.pgt.21010.

摘要

电解制氢能够将不稳定的可再生能源转化为氢能，实现大规模、季节性储能，是助力实现我国碳中和目标的关键手段之一。对高温固体氧化物电解制氢技术进行了探讨与研究，介绍了高温固体氧化物电解的工作原理；针对其实际运行特性，建立了电解过程电化学模型与热力学模型，并通过与实验数据对比验证了模型的有效性；进一步地，分析了电流密度和操作温度对高温固体氧化物电解极化损失的影响，研究了高温电解过程热力学性能的变化情况。结果表明：在高温下对固体氧化物电解进行整体热集成与热管理，有利于减少电能消耗；若将高温电解过程与其他工业过程相结合，利用低品位的工业余热或废热，则能够进一步提升高温固体氧化物电解的整体能效。

Abstract

Water electrolysis can transform unstable renewable energy into the hydrogen energy and realize large-scale and seasonal energy storage

which is one of the key means to achieve the goal of "carbon neutrality" in China. The technology of high temperature solid oxide electrolysis cell (SOEC) was discussed and studied

and the working principle of the high temperature solid oxide electrolysis was introduced. According to its actual operation characteristics

the electrochemical model and thermodynamic model of electrolysis process were established

and the models were verified by comparing with the experimental data. Furthermore

the effects of current density and operating temperature on the high temperature solid oxide electrolysis were analyzed

and the thermodynamic analysis was conducted. The results show that the thermal integration and management of SOEC at high temperature will be conducive to reduce the power consumption. If the high-temperature electrolysis process is combined with other industrial processes and utilized the low-grade industrial waste heat

the overall efficiency of high-temperature solid oxide electrolysis is expected to be further improved.

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references

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