Research Progress of Multifunctional Lignin-based Materials

Ma Ming-guo; Yuan Qi

doi:10.12052/gdutxb.210118

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Research Progress of Multifunctional Lignin-based Materials

更新时间：2026-05-27

- Research Progress of Multifunctional Lignin-based Materials
- Vol. 39, Issue 1, Pages: 14-20, 62(2022)
- 作者机构：
  
  北京林业大学材料科学与技术学院,北京,100083
- 作者简介：
- 基金信息：
- DOI：10.12052/gdutxb.210118
  CLC： S216.3
- Online First：25 January 2022，
  
  Published：2022
- 稿件说明：
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马明国, 袁琪. 基于木质素的多功能材料应用研究进展[J]. 广东工业大学学报, 2022, 39(1): 14-20, 62.

Ma Ming-guo, Yuan Qi. Research Progress of Multifunctional Lignin-based Materials[J]. 2022, 39(1): 14-20, 62.
马明国, 袁琪. 基于木质素的多功能材料应用研究进展[J]. 广东工业大学学报, 2022, 39(1): 14-20, 62. DOI： 10.12052/gdutxb.210118.

Ma Ming-guo, Yuan Qi. Research Progress of Multifunctional Lignin-based Materials[J]. 2022, 39(1): 14-20, 62. DOI： 10.12052/gdutxb.210118.

摘要

木质素结构复杂

来源广泛

价格低廉

是自然界可再生的酚类聚合物。木质素可以转化为能源、化学品及多功能材料

具有广阔的潜在应用前景。本文简单地介绍了木质素的分离、结构与基本性质

综述了基于木质素的多功能材料研究进展

尤其是依托典型案例介绍了基于木质素的多功能材料在能源、环境、传感以及碳达峰碳中和等领域中的研究进展。最后

对多功能木质素材料存在的问题和潜在的发展方向给予了建议，以期为基于木质素的多功能材料的资源化和高值化应用提供途径和思路。

Abstract

Lignin has a wide range of sources

low price

and complex structure. It is a renewable phenolic polymer in nature. It can be transformed into energy

chemicals

and functional materials

and has a potential application prospect. The research progress of multifunctional lignin materials is reviewed

especially based on typical examples

and the progress of lignin in the fields of energy

environment

sensing and carbon peak and carbon neutralization discussed. Finally

the problems and potential development direction of multifunctional lignin materials are proposed based on our knowledge. Solutions and theoretical support are provided for the applications of multifunctional lignin-based materials.

关键词

Keywords

references

RALPH J, LAPIERRE C, BOERJAN W. Lignin structure and its engineering [J]. Current Opinion in Biotechnology, 2019, 56: 240-249.

YANG H T, YU B, XU X D, et al . Lignin-derived bio-based flame retardants toward high-performance sustainable polymeric materials [J ] . Green Chemistry, 2020, 22: 2129-2161.

LIU C, WU S L, ZHANG H Y, et al . Catalytic oxidation of lignin to valuable biomass-based platform chemicals: a review [J ] . Fuel Processing Technology, 2019, 191: 181-201.

LI S M, SUN S L, MA M G, et al . Lignin-based carbon/CePO 4 nanocomposites: solvothermal fabrication, characterization, thermal stability, and luminescence [J ] . Biores ources, 2013, 8: 4155-4170.

LI S X, LI M F, BING J, WU X F, et al . Preparation of organic acid lignin submicrometer particle as a natural broad-spectrum photo-protection agent [J ] . International Journal of Biological Macromolecules, 2019, 132: 836-843.

LIU R, DAI L, XU C L, et al . Lignin-based micro- and nanomaterials and their composites in biomedical applications [J ] . ChemSusChem, 2020, 13: 4266-4283.

WANG H L, PU Y Q, RAGAUSKAS A, et al . From lignin to valuable products-strategies, challenges, and prospects [J ] . Bioresource Technology, 2019, 271: 449-461.

PONNUSAMY V K, NGUYEN D D, DHARMARAJA J, et al . A review on lignin structure, pretreatments, fermentation reactions and biorefinery potential [J ] . Bioresource Technology, 2019, 271: 462-472.

SONG G Y. The development of catalytic fractionation and conversion of lignocellulosic biomass under lignin-first strategy [J]. Journal of Forestry Engineering, 2019, 4(5): 1-10.

DENG J, SUN S F, ZHU E Q, et al . Sub-micro and nano-lignin materials: small size and rapid progress [J ] . Industrial Crops Products, 2021, 164: 113412.

SHI Z J, MA M G. Synthesis, structure, and applications of lignin-based carbon materials: a review [J]. Science of Advanced Materials, 2019, 11: 18-32.

MA C, KIM T H, LIU K, et al . Multifunctional lignin-based composite materials for emerging applications [J ] . Frontiers in Bioengineering and Biotechnology, 2021, 9: 708976.

陈小红. Rh(Ⅲ)催化含氮有机物与重氮化合物的偶联反应 [D]. 北京: 北京林业大学, 2018.

孙建奎. 基于木质素优先的催化解聚及生物质全组分分级转化[D]. 北京: 北京林业大学, 2019.

李赫龙. 后过渡金属催化木质素氢解路线及机理研究[D]. 北京: 北京林业大学, 2020.

陈雪. 速生生物质半纤维素及木质素组分转化为化学品研究[D]. 北京: 北京林业大学, 2020.

毛健贞. 乌拉草木质素结构解析及预处理过程中的木质素结构变化[D]. 北京: 北京林业大学, 2014.

RENCORET J, PRINSEN P, GUTIERREZ A, et al . Isolation and structural characterization of the mill ed wood lignin, dioxane lignin, and cellulolytic lignin preparations from brewer's spent grain [J ] . Journal of Agricultural and Food Chemistry, 2015, 63: 603-613.

ANDO D, NAKATSUBO T, TAKANO T, et al . Multi-step degradation method for beta-O-4 linkages in lignins: gamma-TTSA method. Part 3. Degradation of milled wood lignin (MWL) from Eucalyptus globulus [J ] . Holzforschung, 2013, 67: 835-841.

JUNG H G, MERTENS D R, PAYNE, A J. Correlation of acid detergent lignin and Klason lignin with digestibility of forage dry matter and neutral detergent fiber [J]. Journal of Dairy Science, 1997, 80: 1622-1628.

YE Q Q, YOKOYAMA T. Revisiting the mechanism of beta-O-4 bond cleavage during acidolysis of lignin VII: acidolyses of non-phenolic C-6-C-2-type model compounds using HBr, HCl and H2SO4, and a proposal on the characteristic action of Br- and Cl- [J]. Journal of Wood Science, 2020, 66: 80.

GUERRA A, FILPPONEN I, LUCIA L A, et al . Toward a better understanding of the lignin isolation process from wood [J ] . Journal of Agricultural and Food Chemistry, 2006, 54: 5939-5947.

LIAO J J, ABD LATIF N H, TRACHE D, et al . Current advancement on the isolation, characterization and application of lignin [J ] . I nternational Journal of Biological Macromolecules, 2020, 162: 985-1024.

COLOMBO S M, ZHANG Z, WONG D F, et al . Hydrolysis lignin as a multifunctional additive in Atlantic salmon feed improves fish growth performance and pellet quality and shifts gut microbiome [J ] . Aquaculture Nutrition, 2020, 26: 1353-1368.

李立霞. 多级孔分子筛负载铜基催化剂的制备及其催化木质素选择性氧化解聚[D]. 广州: 华南理工大学, 2020.

李章敏. 金属基离子液体定向解聚木质素制备高值化学品的研究[D]. 广州: 华南理工大学, 2018.

邵鲁鹏. 工业木质素热化学转化制备芳香化学品的研究[D]. 北京: 北京林业大学, 2018.

高士帅. 木质素衍生物改性脲醛树脂的机制及其性能研究[D]. 北京: 北京林业大学, 2020.

蔡诚. pH响应木质素表面活性剂的合成及其在木质纤维素酶解和酶回收中的应用[D]. 广州: 华南理工大学, 2020.

秦延林. 羟丙基磺化碱木质素染料分散剂及草酸预处理制备纳米纤维素的研究[D]. 广州: 华南理工大学, 2016.

武颖. 木质素天然高分子紫外防护剂的广谱化改性及微结构调控[D]. 广州: 华南理工大学, 2020.

李涛. 木质素基多功能缓控释肥料的制备及其性能研究[D]. 兰州: 兰州大学, 2019.

贺晓艳. 改性纳米木质素增强可降解聚合物薄膜性能研究[D]. 哈尔滨: 东北林业大学, 2019.

ZHU J D, YAN C Y, ZHANG X, et al . A sustainable platform of lignin: from bioresources to materials and their applications in rechargeable batteries and supercapacitors [J ] . Progress in Energy and Combustion Science, 2020, 76: 100788.

PARK J H, RANA H H, LEE J Y, et al . Renewable flexible supercapacitors based on all-lignin-based hydrogel electrolytes and nanofiber electrodes [J ] . Journal of Materials Chemistry A, 2019, 7: 16962-16968.

LIU S, MA M G. Lignin-derived nitrogen-doped polyacrylonitrile/polyaniline carbon nanofibers by electrospun method for energy storage [J]. Ionics, 2020, 26(9): 4651-4660.

FU F B, YANG D J, ZHANG W L, et al . Green self-assembly synthesis of porous lignin-derived carbon quasi-nanosheets for high-performance supercapacitors [J ] . Chemical Engineering Journal, 2020, 392: 123721.

JHA S, MEHTA S, CHEN Y, et al . Design and synthesis of lignin-based flexible supercapacitors [J ] . ACS Sustainable Chemistry Engineering, 2020, 8: 498-511.

HEROU S, BAILEY J J, KOK M, et al . High-density lignin-derived carbon nanofiber supercapacitors with enhanced volumetric energy density [J ] . Advanced Science, 2021: 2100016.

LIU H Y, XU T, LIU K, et al . Lignin-based electrodes for energy storage application [J ] . Industrial Crops Products, 2021, 165: 113425.

SUN Y C, WANG T T, SUN X Y, et al . The potential of biochar and lignin-based adsorbents for wastewater treatment: Comparison, mechanism, and application? a review [J ] . Industrial Crops and Products, 2021, 166: 113473.

SUPANCHAIYAMAT N, JETSRISUPARB K, KNIJNENBURG J T N, et al . Lignin materials for adsorption: current trend, perspectives and opportunities [J ] . Bioresource Technology, 2019, 272: 570-581.

LI Y L, WU M, WANG B, et al . Synthesis of magnetic lignin-based hollow microspheres: a highly adsorptive and reusable adsorbent derived from renewable resources [J ] . ACS Sustainable Chemistry Engineering, 2016, 4: 5523-5532.

MA Y Z, ZHENG D F, MO Z Y, et al . Magnetic lignin-based carbon nanoparticles and the adsorption for removal of methyl orange [J ] . Colloids and Surfaces A, 2018, 559: 226-234.

JIANG X Y, WANG G H, LIU Q J, et al . Graft copolymerization of acrylic acid on Kraft lignin to enhance aniline adsorption from aqueous solution [J ] . TAPPI Journal, 2019, 18: 75-84.

DAI L, LI Y T, LIU R, et al . Green mussel-inspired lignin magnetic nanoparticles with high adsorptive capacity and environmental friendliness for chromium (III) removal [J ] . International Journal of Biological Macromolecules, 2019, 132: 478-486.

SUI W J, PANG T R, WANG G H, et al . Stepwise ethanol-water fractionation of enzymatic hydrolysis lignin to improve its performance as a cationic dye adsorbent [J ] . Molecules, 2020, 25: 2603.

MENG L Y, MA M G, JI X X. Preparation of lignin-based carbon materials and its application as a sorbent [J]. Materials, 2019, 12: 1111.

AN L, SI C L, BAE J H, et al . One-step silanization and amination of lignin and its adsorption of Congo red and Cu(II) ions in aqueous solution [J ] . International Journal of B iological Macromolecules, 2020, 159: 222-230.

CHOKKAREDDY R, REDHI G G, KARTHICK T. A lignin polymer nanocomposite based electrochemical sensor for the sensitive detection of chlorogenic acid in coffee samples [J]. Heliyon, 2019, 5: e01457.

YUN X J, ZHANG Q T, LUO B, et al . Fabricating flexibly resistive humidity sensors with ultra-high sensitivity using carbonized lignin and sodium alginate [J ] . Electroanalysis, 2020, 32: 2282-2289.

WANG Q H, PAN X F, LIN C M, et al . Biocompatible, self-wrinkled, antifreezing and stretchable hydrogel-based wearable sensor with PEDOT: sulfonated lignin as conductive materials [J ] . Chemical Engineering Journal, 2019, 370: 1039-1047.

WANG Q H, PAN X F, GUO J J, et al . Lignin and cellulose derivatives-induced hydrogel with asymmetrical adhesion, strength, and electriferous properties for wearable bioelectrodes and self-powered sensors [J ] . Chemical Engineering Journal, 2021, 414: 128903.

WANG Q H, LAN J X, HUA Z F, et al . An oriented Fe 3+ -regulated lignin-based hydrogel with desired softness, conductivity, stretchability, and asymmetric adhesiveness towards anti-interference pressure sensors [J ] . International Journal of Biological Macromol ecules, 2021, 184: 282-288.

HAN X, LV Z L, RAN F L, et al . Green and stable piezoresistive pressure sensor based on lignin-silver hybrid nanoparticles/polyvinyl alcohol hydrogel [J ] . International Journal of Biological Macromolecules, 2021, 176: 78-86.

WANG F, GAO C H, ZHANG W L, et al . Industrial structure optimization and low-carbon transformation of Chinese industry based on the forcing mechanism of CO 2 emission peak target [J ] . Sustainability, 2021, 13: 4417.

NWACHUKWU C M, WANG C, WETTERLUND E. Exploring the role of forest biomass in abating fossil CO 2 emissions in the iron and steel industry—the case of Sweden [J ] . Applied Energy, 2021, 288: 116558.

QUACOE D, WEN X Z, QUACOE D. Nexus among biomass consumption, economic growth, and CO 2 emission based on the moderating role of biotechnology: evidence from China [J ] . Environmental Science and Pollution Research, 2021, 28: 15755-15767.

BAUER N, KLEIN D, HUMPENODER F, et al . Bio-energy and CO 2 emission reductions: an integrated land-use and energy sector perspective [J ] . Climatic Change, 2020, 163: 1675-1693.

SULAIMAN C, ABDUL-RAHIM A S. Can clean biomass energy use lower CO 2 emissions in African economies? empirical evidence from dynamic long-run panel framework [J ] . Environmental Science and Pollution Research, 2020, 27: 37699-37708.

DESSBESELL L, PALEOLOGOU M, LEITCH M, et al . Global lignin supply overview and Kraft lignin potential as an alternative for petroleum-based polymers [J ] . Renewable Sustainable Energy Reviews, 2020, 123: 109768.

LI D Z, HUANG G Y, ZHU S Y, et al . How to peak carbon emissions of provincial construction industry? scenario analysis of Jiangsu Province [J ] . Renewable Sustainable Energy Reviews, 2021, 144: 110953.

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