Research Progress of MOF/Bismuth-based Semiconductor Composites in Photocatalytic Technology

Cao Yi-ting; Wang Qiao; Xu Ze-tao; Lyu Guan-heng

doi:10.12052/gdutxb.210058

English Version Journal Login

您当前的位置：

首页 >

文章列表页 >

Research Progress of MOF/Bismuth-based Semiconductor Composites in Photocatalytic Technology

更新时间：2026-05-27

- Research Progress of MOF/Bismuth-based Semiconductor Composites in Photocatalytic Technology
- Vol. 39, Issue 4, Pages: 113-120(2022)
- 作者机构：
  
  1. 广东工业大学土木与交通工程学院,广东,广州,510006
  2. 哈尔滨工业大学城市水资源与水环境国家重点实验室,黑龙江,哈尔滨,150090
- 作者简介：
- 基金信息：
- DOI：10.12052/gdutxb.210058
  CLC： O643.3
- Online First：10 July 2022，
  
  Published：2022
- 稿件说明：
移动端阅览
曹怡婷, 王俏, 许泽涛, 吕冠衡. 金属有机框架/铋基复合材料的光催化技术应用研究进展[J]. 广东工业大学学报, 2022, 39(4): 113-120.

Cao Yi-ting, Wang Qiao, Xu Ze-tao, et al. Research Progress of MOF/Bismuth-based Semiconductor Composites in Photocatalytic Technology[J]. 2022, 39(4): 113-120.
曹怡婷, 王俏, 许泽涛, 吕冠衡. 金属有机框架/铋基复合材料的光催化技术应用研究进展[J]. 广东工业大学学报, 2022, 39(4): 113-120. DOI： 10.12052/gdutxb.210058.

Cao Yi-ting, Wang Qiao, Xu Ze-tao, et al. Research Progress of MOF/Bismuth-based Semiconductor Composites in Photocatalytic Technology[J]. 2022, 39(4): 113-120. DOI： 10.12052/gdutxb.210058.

摘要

光催化技术在环境修复和能源转换方面极具潜力，其核心为高效光催化剂的设计和开发。铋基半导体和金属有机框架(Metal-organic Frameworks，MOFs)材料耦合形成的复合材料具有优异的光催化活性，逐渐成为备受研究人员关注的一类热点材料。本文重点介绍了MOF/铋基半导体复合材料(MOF/Bismuth-based Semiconductor Composites，MBCs)的制备方法；继而论述了MBCs在有机污染物降解、Cr(VI)还原、光解水、合成氨等方面的应用。最后，指出了现阶段MBCs光催化中存在的问题，并展望了未来MBCs光催化技术领域的发展方向。

Abstract

Photocatalysis has been regarded as an efficient technology in environmental remediation and energy conversion

and its core is the design and development of efficient photocatalysts. The composites of the bismuth-based semiconductors combined with metal-organic frameworks (MOFs) have attracted much attention due to their high photocatalytic activity. A review is conducted on recent advances in MOF/bismuth-based semiconductor composites (abbreviated as MBCs). On this basis

the synthesis methods of MBCs are described in detail

and then the applications of MBCs in organic pollutant degradation

Cr(VI) reduction

water (H

O) splitting

nitrogen (N

) fixation discussed. Finally

the unsolved problems of MBCs are discussed and the future development prospects proposed.

关键词

Keywords

references

WU T, LIU X, LIU Y, et al . Application of QD-MOF composites for photocatalysis: energy production and environmental remediation [J ] . Coordination Chemistry Reviews, 2020, 403: 213097.

OLA O, MAROTO-VALER M M. Review of material design and reactor engineering on TiO 2 photocatalysis for CO 2 reduction [J ] . Journal of Photochemistry and Photobiology C:Photochemistry Reviews, 2015, 24: 16-42.

TRELLU C, MOUSSET E, PECHAUD Y, et al . Removal of hydrophobic organic pollutants from soil washing/flushing solutions: a critical review [J ] . Journal of Hazardous Materials, 2016, 306: 149-174.

REDDY P A K, REDDY P V L, KWON E, et al . Recent advances in photocatalytic treatment of pollutants in aqueous media [J ] . Environment International, 2016, 91: 94-103.

MAEDA K, TERAMURA K, LU D L, et al . Photocatalyst releasing hydrogen from water- enhancing catalytic performance holds promise for hydrogen production by water splitting in sunlight [J ] . Nature, 2006, 440(7082): 295-295.

LIANG Q, LIU X, ZENG G, et al . Surfactant-assisted synthesis of photocatalysts: mechanism, synthesis, recent advances and environmental application [J ] . Chemical Engineering Journal, 2019, 372: 429-451.

LI H, EDDAOUDI M, O'KEEFFE M, et al . Design and synthesis of an exceptionally stable and highly porous metal-organic framework [J ] . Nature, 1999, 402(6759): 276-279.

YAGHI O M, O'KEEFFE M, OCKWIG N W, et al . Reticular synthesis and the design of new materials [J ] . Nature, 2003, 423(6941): 705-714.

FURUKAWA H, CORDOVA K E, O'KEEFFE M, et al . The chemistry and applications of metal-organic frameworks [J ] . Science, 2013, 341(6149): 1230444.

HUANG G, CHEN Y Z, JIANG H L. Metal-organic frameworks for catalysis [J]. Acta Chimica Sinica, 2016, 74(02): 113-129.

WENG H, YAN B. Flexible Tb(III) functionalized cadmium metal organic framework as fluorescent probe for highly selectively sensing ions and organic small molecules [J]. Sensors and Actuators B-Chemical, 2016, 228: 702-708.

ZHU J, XIA T, CUI Y, et al . A turn-on MOF-based luminescent sensor for highly selec tive detection of glutathione [J ] . Journal of Solid State Chemistry, 2019, 270: 317-323.

AL-NADDAF Q, ROWNAGHI A A, REZAEI F. Multicomponent adsorptive separation of CO 2 , CO, CH 4 , N 2 , and H 2 over core-shell zeolite-5A@MOF-74 composite adsorbents [J ] . Chemical Engineering Journal, 2020, 384: 123251.

SUN H, YU X, MA X, et al . MnO x -CeO 2 catalyst derived from metal-organic frameworks for toluene oxidation [J ] . Catalysis Today, 2020, 355: 580-586.

LI X, ZHU Q L. MOF-based materials for photo- and electrocatalytic CO 2 reduction [J ] . EnergyChem, 2020, 2(3): 100033.

ZHAO C, PAN X, WANG Z, et al . 1 + 1 2: a critical review of MOF/bismuth-based semiconductor composites for boosted photocatalysis [J ] . Chemical Engineering Journal, 2021, 417: 128022.

HE R, XU D, CHENG B, et al . Review on nanoscale Bi-based photocatalysts [J ] . Nanoscale Horizons, 2018, 3(5): 464-504.

CHEN D D, YI X H, WANG C C. Preparation of metal-organic frameworks and their composites using mechanochemical methods [J]. Chinese Journal of Inorganic Chemistry, 2020, 36(10): 1805-1821.

BIBI R, SHEN Q, WEI L, et al . Hybrid BiOBr/UiO-66-NH 2 composite with enhanced visible-light driven photocatalytic activity toward RhB dye degradation [J ] . RSC Advances, 2018, 8(4): 2048-2058.

HU Q, CHEN Y, LI M, et al . Construction of NH 2 -UiO-66/BiOBr composites with boosted photocatalytic activity for the removal of contaminants [J ] . Colloids and Surfaces A:Physicochemical and Engineering Aspects, 2019, 579: 123625.

KHASEVANI S G, GHOLAMI M R. Engineering a highly dispersed core@shell structure for efficient photocatalysis: a case study of ternary novel BiOI@MIL-88A(Fe)@g-C 3 N 4 nanocomposite [J ] . Materials Research Bulletin, 2018, 106: 93-102.

ASKARI N, BEHESHTI M, MOWLA D, et al . Fabrication of CuWO 4 /Bi 2 S 3 /ZIF67 MOF: a novel double Z-scheme ternary heterostructure for boosting visible-light photodegradation of antibiotics [J ] . Chemosphere, 2020, 251: 126453.

LI H, ZHAO C, LI X, et al . Boosted photocatalytic Cr(VI) reduction over Z-scheme MIL-53(Fe)/Bi 12 O 17 Cl 2 composites under white light [J ] . Journal of Alloys and Compounds, 2020, 844: 156147.

ZHAO C, WANG J, CHEN X, et al . Bifunctional Bi 12 O 17 Cl 2 /MIL-100(Fe) composites toward photocatalytic Cr(VI) sequestration and activation of persulfate for bisphenol A degradation [J ] . Science of the Total Environment, 2021, 752: 141901.

YANG Z, DING J, FENG J, et al . Preparation of BiVO 4 /MIL‐125 (Ti) composite with enhanced visible‐light photocatalytic activity for dye degradation [J ] . Applied Organometallic Chemistry, 2018, 32(4): e4285.

HE Y P, JIN X Y, LI W Z, et al . Synthesis and photocatalytic properties of Bi 2 WO 6 /UiO-66 composite [J ] . Chinese Journal of Inorganic Chemistry, 2019, 35(6): 996-1004.

LI J M, TUO X J, LI X M, et al . Photocatalytic degradation of crystal violet using BiVO 4 /MIL-100(Fe) composites [J ] . Fine Chemicals, 2020, 37(1): 33-38.

KHASEVANI S G, GHOLAMI M R. Evaluation of the reaction mechanism for photocatalytic degradation of organic pollutants with MIL-88A/BiOI structure under isible light irradiation [J]. Research on Chemical Intermediates, 2019, 45(3): 1341-1356.

ASKARI N, BEHESHTI M, MOWLA D, et al . Fabrication of CuWO 4 /Bi 2 S 3 /ZIF-67 MOF: a novel double Z-scheme ternary heterostructure for boosting visible-light photodegradation of antibiotics [J ] . Chemosphere, 2020, 251: 126453.

TANG L, LV Z Q, XUE Y C, et al . MIL-53 (Fe) incorporated in the lamellar BiOBr: Promoting the visible-light catalytic capability on the degradation of rhodamine B and carbamazepine [J ] . Chemical Engineering Journal, 2019, 374: 975-982.

HU Q, DI J, WANG B, et al . In-situ preparation of NH 2 -MIL-125(Ti)/BiOCl composite with accelerating charge carriers for boosting visible light photocatalytic activity [J ] . Applied Surface Science, 2019, 466: 525-534.

LIANG Q, CUI S, JIN J, et al . Fabrication of BiOI@UIO-66(NH 2 )@g-C 3 N 4 ternary Z-scheme heterojunction with enhanced visible-light photocatalytic activity [J ] . Applied Surface Science, 2018, 456: 899-907.

QI Y W, WEI L H, SHI D N, et al . Preparation of UiO-66/BiVO 4 composite photocatalyst and its photodegradation of tetracycline [J ] . China Environmental Science, 2021, 41(3): 1162-1171.

ZHAO C, WANG Z, LI X, et al . Facile fabrication of BUC-21/Bi 24 O 31 Br 10 composites for enhanced photocatalytic Cr(VI) reduction under white light [J ] . Chemical Engineering Journal, 2020, 389: 123431.

ZHANG S, DU M, KUANG J, et al . Surface-defect-rich mesoporous NH 2 -MIL-125 (Ti)@Bi 2 MoO 6 core-shell heterojunction with improved charge separation and enhanced visible-light-driven photocatalytic performance [J ] . Journal of Colloid and Interface Science, 2019, 554: 324-334.

HAN Q, DONG Y, XU C, et al . Immobilization of Metal-Organic Framework MIL-100(Fe) on the Surface of BiVO 4 : a new platform for enhanced visible-light-driven water oxidation [J ] . ACS Applied Materials Interfaces, 2020, 12(9): 10410-10419.

LIU J X, LI R, ZU X, et al . Photocatalytic conversion of nitrogen to ammonia with water on triphase interfaces of hydrophilic-hydrophobic composite Bi 4 O 5 Br 2 /ZIF-8 [J ] . Chemical Engineering Journal, 2019, 371: 796-803.

LOPEZ Y C, VILTRES H, GUPTA N K, et al . Transition metal-based metal-organic frameworks for environmental applications: a review [J ] . Environmental Chemistry Letters, 2021: 1-40.

TARKWA J B, OTURAN N, ACAYANKA E, et al . Photo-Fenton oxidation of Orange G azo dye: process optimization and mineralization mechanism [J ] . Environmental Chemistry Letters, 2019, 17(1): 473-479.

DONG Z, LIU L, HAO Y, et al . Research progress on the treatment of azo dye containing wastewater [J ] . Technology of Water Treatment, 2017, 43(4): 6-10.

YANG H M, LIU X, SONG X L, et al . In situ electrochemical synthesis of MOF-5 and its application in improving photocatalytic activity of BiOBr [J ] . Transactions of Nonferrous Metals Society of China, 2015, 25(12): 3987-3994.

MUGUNTHAN E, SAIDUTTA M B, JAGADEESHBABU P E. Visible light assisted photocatalytic degradation of diclofenac using TiO 2 -WO 3 mixed oxide catalysts [J ] . Environmental Nanotechnology, Monitoring Management, 2018, 10: 322-330.

LI G, NIE X, CHEN J, et al . Enhanced simultaneous PEC eradication of bacteria and antibiotics by facilely fabricated high-activity facets TiO 2 mounted onto TiO 2 nanotubular photoanode [J ] . Water Research, 2016, 101: 597-605.

KARKMAN A, PARNANEN K, LARSSON D G J. Fecal pollution can explain antibiotic resistance gene abundances in anthropogenically impacted environments [J]. Nature Communications, 2019, 10(1): 80.

BANASCHIK R, LUKES P, JABLONOWSKI H, et al . Potential of pulsed corona discharges generated in water for the degradation of persistent pharmaceutical residues [J ] . Water Research, 2015, 84: 127-35.

WANG X P, ZHU H B. Liquid chromatographic analysis of 14 kinds of afloxacin antibiotics in pharmaceutical industrial wastewater [J]. Industrial Water Treatment, 2019, 39(7): 89-93.

WANG C C, DU X D, LI J, et al . Photocatalytic Cr(VI) reduction in metal-organic frameworks: a mini-review [J ] . Applied Catalysis B:Environmental, 2016, 193: 198-216.

WANG X J, ZHU X P, LAN L M. Efficient removal of Cr(Vl) in wastewater by Mg/Al layered superamolecular compounds [J]. Chinese Journal of Applied Chemistry, 2017, 34(1): 98-104.

HAO X, JIN Z, YANG H, et al . Peculiar synergetic effect of MoS 2 quantum dots and graphene on metal-organic frameworks for photocatalytic hydrogen evolution [J ] . Applied Catalysis B:Environmental, 2017, 210: 45-56.

BLAKEMORE J D, CRABTREE R H, BRUDVIG G W. Molecular catalysts for water oxidation [J]. Chemical Reviews, 2015, 115(23): 12974-3005.

JI Y J, CAO T P, ZHAO Y H, et al . Preparation of Bi@Bi 2 Sn 2 O 7 /TiO 2 plasmonic composite fibers with enhanced photocatalytic hydrogen generation activity [J ] . Chinese Journal of Inorganic Chemistry, 2019, 35(8): 1371-1378.

OSHIKIRI T, UENO K, MISAWA H. Plasmon-induced ammonia synthesis through nitrogen photofixation with visible light irradiation [J]. Angewandte Chemie, 2014, 126(37): 9960-9963.

WANG L, XIA M, WANG H, et al . Greening ammonia toward the solar ammonia refinery [J ] . Joule, 2018, 2(6): 1055-1074.

HIRAKAWA H, HASHIMOTO M, SHIRAISHI Y, et al . Photocatalytic conversion of nitrogen to ammonia with water on surface oxygen vacancies of titanium dioxide [J ] . Journal of the American Chemical Society, 2017, 139(31): 10929-10936.

VAN DER HAM C J M, KOPER M T M, HETTERSCHEID D G H. Challenges in reduction of dinitrogen by proton and electron transfer [J]. Chemical Society Reviews, 2014, 43(15): 5183-5191.

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

A Study of the Modification of Nano-CuO Photocatalyst by Ethanol Quenching

Degradation of Reactive Black Dye GR in Engineering Photocatalytic Reactors Coated with TiC2

A Study of Power Quality Regulation Strategies of Energy Storage Converters

Modeling of 3D NAND Memory Cells with Taper Angle and Programming Strategy Optimization

Efficient Temporal Modeling for RGB-T Tracking

Related Author

Hu Lu-guo

Hu Zheng-fa

Xiao Yang

Wang Yin-hai

Zhao Hui

FU Li-Peng

ZHANG Guo-Qing

YANG Cheng-Zhao

Related Institution

广东工业大学物理与光电工程学院

东源广工大现代产业协同创新研究院

AI问答

⁰