A Study of the Preparation and Photoluminescence of Copolymers of Vinyl Carbazole and 4-(1-adamantyl) Styrene

Liu Ying-chun; Guo Jian-wei; Luo Tao; Wu Tong-biao

doi:10.12052/gdutxb.170136

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A Study of the Preparation and Photoluminescence of Copolymers of Vinyl Carbazole and 4-(1-adamantyl) Styrene

更新时间：2026-05-27

- A Study of the Preparation and Photoluminescence of Copolymers of Vinyl Carbazole and 4-(1-adamantyl) Styrene
- Vol. 35, Issue 1, Pages: 73-76(2018)
- 作者机构：
  
  1. 广东工业大学　轻工化工学院,广东,广州,510006
  2. 中山火炬职业技术学院　生物医药系,广东,中山,528437
- 作者简介：
- 基金信息：
- DOI：10.12052/gdutxb.170136
  CLC： O632
- Online First：09 January 2018，
  
  Published：2018
- 稿件说明：
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柳滢春, 郭建维, 罗涛, 吴彤彪. （乙烯基咔唑-对金刚烷基苯乙烯）共聚物的合成与光致发光性能[J]. 广东工业大学学报, 2018, 35(1): 73-76.

Liu Ying-chun, Guo Jian-wei, Luo Tao, et al. A Study of the Preparation and Photoluminescence of Copolymers of Vinyl Carbazole and 4-(1-adamantyl) Styrene[J]. 2018, 35(1): 73-76.
柳滢春, 郭建维, 罗涛, 吴彤彪. （乙烯基咔唑-对金刚烷基苯乙烯）共聚物的合成与光致发光性能[J]. 广东工业大学学报, 2018, 35(1): 73-76. DOI： 10.12052/gdutxb.170136.

Liu Ying-chun, Guo Jian-wei, Luo Tao, et al. A Study of the Preparation and Photoluminescence of Copolymers of Vinyl Carbazole and 4-(1-adamantyl) Styrene[J]. 2018, 35(1): 73-76. DOI： 10.12052/gdutxb.170136.

摘要

以1-(4-溴苯基)金刚烷为原料

经醛化反应和Wittig反应合成了单体对金刚烷基苯乙烯. 然后通过对金刚烷基苯乙烯和乙烯基咔唑的共聚

合成了不同金刚烷摩尔含量的共聚物(乙烯基咔唑-对金刚烷基苯乙烯). 采用FTIR、

HNMR和元素分析等对各产物及共聚物结构进行了表征

通过凝胶色谱仪和荧光光谱仪考察了金刚烷含量对共聚物分子量和光学性能的影响. 结论表明

金刚烷基团的引入

共聚物的发光色纯度和发光效率均有提高.

Abstract

The 4-(1-adamantyl) styrene was synthesized by the hydroformylation reaction and Wittig reaction with 1-(4-bromophenyl) adamantane as raw material. And then the copolymer p(NVK-co-AdSt) with different content of adamantane were prepared by copolymerization of 4-(1-adamantyl) styrene and vinyl carbazole. The structures of the products and copolymers were characterized by FTIR

HNMR and elemental analysis. The effects of adamantane content on the molecular weight and optical properties of the copolymers were investigated by gel chromatography and fluorescence spectroscopy. The results showed that the introduction of adamantane groups

the color purity and luminous efficiency of the copolymers were improved.

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references

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