A Research of Mesoporous Copper-Manganese Mixed Oxides for Selective Oxidation of Benzyl Alcohol to Benzaldehyde

Zheng Hai-long; Liao Shu-huan; Yu Lin

doi:10.12052/gdutxb.160025

English Version Journal Login

您当前的位置：

首页 >

文章列表页 >

A Research of Mesoporous Copper-Manganese Mixed Oxides for Selective Oxidation of Benzyl Alcohol to Benzaldehyde

更新时间：2026-05-27

- A Research of Mesoporous Copper-Manganese Mixed Oxides for Selective Oxidation of Benzyl Alcohol to Benzaldehyde
- Vol. 34, Issue 2, Pages: 28-33(2017)
- 作者机构：
- 作者简介：
- 基金信息：
- DOI：10.12052/gdutxb.160025
  CLC： TQ244
- Online First：09 March 2017，
  
  Published：2017
- 稿件说明：
移动端阅览
郑海龙, 廖菽欢, 余林. 介孔Cu-Mn复合氧化物催化氧化苯甲醇合成苯甲醛的研究[J]. 广东工业大学学报, 2017, 34(2): 28-33.

Zheng Hai-long, Liao Shu-huan, Yu Lin. A Research of Mesoporous Copper-Manganese Mixed Oxides for Selective Oxidation of Benzyl Alcohol to Benzaldehyde[J]. 2017, 34(2): 28-33.
郑海龙, 廖菽欢, 余林. 介孔Cu-Mn复合氧化物催化氧化苯甲醇合成苯甲醛的研究[J]. 广东工业大学学报, 2017, 34(2): 28-33. DOI： 10.12052/gdutxb.160025.

Zheng Hai-long, Liao Shu-huan, Yu Lin. A Research of Mesoporous Copper-Manganese Mixed Oxides for Selective Oxidation of Benzyl Alcohol to Benzaldehyde[J]. 2017, 34(2): 28-33. DOI： 10.12052/gdutxb.160025.

摘要

采用无模板共沉淀法合成介孔Cu-Mn复合氧化物，该氧化物具有很高的比表面积且可大量合成.该复合氧化物（Cu-Mn-

，

=1，2，4）作为催化剂应用在以O

为氧化剂，甲苯为溶剂的苯甲醇选择性氧化合成苯甲醛的研究中，发现该催化剂显示出很高的活性.当

（Cu）：

（Mn）的设计比例为1：2时活性最高，在102℃的温度下，苯甲醇转化率达到90%时仅需20 min，选择性达到98%.催化剂的物理化学特性采用了XRD、SEM、TEM、BET、H

-TPR和EDS技术进行表征.结果表明，Cu和Mn具有协同促进作用，能够互相提高催化活性，但必须控制在一定的比例范围内；另外催化剂的活性与用量关系很大，量越大活性越高.

Abstract

A novel template-free co-precipitation method was applied to synthesize mesoporous copper-manganese mixed oxides with high surface area

which can be obtained in large quantities. Catalytic activity of copper-manganese mixed oxides (Cu-Mn-

4) has been studied in selective oxidation of benzyl alcohol using molecular oxygen as oxidizing agent and toluene as solvent. The catalysts exhibited highest activity

in which 90% conversion of the benzyl alcohol was achieved with 98% selectivity to benzaldehyde within a short reaction period only in 20 min at 102℃

when the design mole ratio of Cu/Mn was 1:2. The

physicochemical properties of the catalysts were characterized by XRD

SEM

TEM

BET

H2-TPR and EDS techniques. It shows that Cu and Mn can improve the catalytic performance each other effectively but there must be an appropriate mole ratio of Cu/Mn. In addition

there is a great relationship between the activity and the amount of catalysts

which shows that the higher activity the more catalysts.

关键词

Keywords

references

张昕, 吴伟伟, 黄启权, 等. 苯甲醇液相氧化制苯甲醛催化剂的研究进展[J]. 石油化工, 2010, 02:215-223.ZHANG X, WU W W, HUANG Q Q, et al. Advance in catalysts for green liquid-phase oxidation of benzyl alcohol to benzaldehyde[J]. Electrochemical Technology, 2010, 02:215-223.

KCKRITZ A, SEBEK M, DITTMAR A, et al. Ru-catalyzed oxidation of primary alcohol[J]. J Mol Catal A:Chem, 2006, 246(1~2):85-99.

STUCHINSKAYA T L, KOZHEVNIKOV I V. Liquid-phase oxidation of alcohols with oxygen catalysed by modified palladium (Ⅱ) oxide[J]. Catal Commum, 2003, 4(8):417-422.

SU F Z, CHEN M, WANG L C, et al. Aerobic oxidation of alcohols catalyzed by gold nanoparticles supported on gallia[J]. Polymorphs Catal Commum, 2008, 9(6):1027-1032.

BEIER M J, HANSEN T W, GRUNWALDT J D. Selective liquid-phase oxidation of alcohols catalyzed by a silver-based catalyst promoted by the presence of ceria[J]. Journal of Catalysis, 2009, 266(2):320-330.

MENG X J, LIN K F, YANG X Y, et al. Catalytic oxidation of olefins and alcohols by molecular oxygen under air pressure over Cu 2 (OH)PO 4 and Cu 4 O(PO4) 2 catalysts[J ] . J Catal, 2003, 218(2):460-464.

CHOUDHARY V R, DUMBRE D K, UPHADE B S, et al. Solvent-free oxidation of benzyl alcohol to benzaldehyde by tert-butyl hydroper oxide using transition metal containing layered double hydroxides and/or mixed hydroxides[J]. J Mol Catal A:Chem, 2004, 215(1-2):129-135.

HU J, SUN K Q, HE D P, et al. Amorphous manganese oxide for catalytic selective oxidation of benzyl alcohol[J]. Chinese Journal of Catalysis, 2007, 28(12):1025-1027.

TANG Q H, HUANG X N, WU C M, et al. Structure and catalytic properties of K-doped manganese oxide supported on alumina[J]. J Mol Catal A:Chem, 2009, 306(1-2):48-53.

SHEN Y F, SUIB S L, O'YONG C L. Cu containing octahedral molecular sieves and octahedral layered materials[J]. J Catal, 1996, 161(1):115-122.

符志伟, 程高, 林婷, 等. 二氧化锰制备及催化燃烧甲苯性能研究[J ] . 广东工业大学学报, 2016, 33(02):85-90.FU Z W, CHENG G, LIN T, et al. The preparation of MnO 2 and application in catalytic combustion of toluene[J ] . Journal of Guangdong University of Technology, 2016, 33(02):85-90.

FANG D, XIE J L. Effect of CuMn 2 O 4 spinel in Cu-Mn oxide catalysts on selective catalytic reduction of NO x with NH 3 at low temperature[J ] . RSC Adv, 2014, 4(49):25540-25551.

TANG W X, WU X F, LI S D. Porous Mn-Co mixed oxide nanorod as a novel catalyst with enhanced catalytic activity for removal of VOCs[J]. Catalysis Communications, 2014, 56(56):134-138.

LI G N, LI L, SHI J J. One-pot pyrolytic synthesis of mesoporous MCo 2 O 4 (4.5)(M=Mn, Ni, Fe, Cu) spinels and its high efficient catalytic properties for CO oxidation at low temperature[J ] . Journal of Molecular Catalysis A-Chemical, 2014, 390(8):97-104.

TANG W X, WU X F, LI S D, et al. Co-nanocasting synthesis of mesoporous Cu-Mn composite oxides and their promoted catalytic activities for gaseous benzene removal[J]. Applied Catalysis B-Environmental, 2015, 162:110-121.

LIU X S, JIN Z N, LU J Q, et al. Highly active CuO/OMS-2 catalysts for low-temperature CO oxidation[J]. Chemical Engineering Journal, 2010, 162(1):151-157.

KRMER M, SCHMIDT T, STWE K, et al. Structural and catalytic aspects of sol-gel derived copper manganese oxides as low-temperature CO oxidation catalyst[J]. Applied Catalysis A:General, 2006, 302(2):257-263.

TANG Q H, GONG X N, ZHAO P Z, et al. Copper-manganese oxide catalysts supported on alumina:Physicochemical features and catalytic performances in the aerobic oxidation of benzyl alcohol[J]. Applied Catalysis A-General, 2010, 389(1-2):101-107.

TANG W X, WU X F, CHEN Y F, et al. Oxalate route for promoting activity of manganese oxide catalysts in total VOCs' oxidation:effect of calcination temperature and preparation method[J]. Mater Chem A, 2014, 2(8):2544-2554.

SHU Z, HUANG W M, SHI J L, et al. Template-free synthesis of mesoporous X-Mn (X=Co, Ni, Zn) bimetal oxides and catalytic application in the room temperature removal of low-concentration NO[J]. Mater Chem A, 2013, 1(35):10218-10227.

ALI R, SIDDIQUI M R, WARTHAN A A. Selective oxidation of benzyl alcohol with molecular oxygen over copper-manganese oxide catalyst[J]. Oxidation Communications, 2011, 34(4):778-787.

PAPAVASILIOU J, AVGOUROPOULOS G, IOANNIDES T. Combined steam reforming of methanol over Cu-Mn spinel oxide catalysts[J]. Journal of Catalysis, 2007, 251(1):7-20.

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Research Progress of Targeted Adsorption-transformation of Emerging Contaminants in Water

A Study of Power Quality Regulation Strategies of Energy Storage Converters

A Resource Allocation Optimization Method for Multi-UAV Integrated Sensing, Computing, and Communication Towards Disaster Relief

The Cross-twin Physics-informed Neural Network for Wave Equations with Conserved Quantities

Research on Foreign Object Detection in Power Transmission Lines Based on the AAGV-YOLOX Model

Related Author

Yang Wen-jian

Lai Yang-yu

Yang Kui

Zu Dao-yuan

Zhang Yuan

Ma Jin-xing

Related Institution

Key Laboratory for City Cluster Environmental Safety and Green Development of the Ministry of Education, School of Ecology, Environment and Resources, Guangdong University of Technology

School of Environmental Science and Engineering, Guangdong University of Technology

Advanced Interdisciplinary Institute of Environment and Ecology, Beijing Normal University

AI问答

⁰