Guanjun Zhang. Effect of accelerator on properties of epoxy resin re-prepared from alcoholysis recycling[J]. High Voltage, 2025, 10(1).
DOI:
Guanjun Zhang. Effect of accelerator on properties of epoxy resin re-prepared from alcoholysis recycling[J]. High Voltage, 2025, 10(1). DOI: 10.1049/hve2.12481.
Effect of accelerator on properties of epoxy resin re-prepared from alcoholysis recycling
摘要
Alcoholysis has emerged as a crucial method for the degradation of anhydride-cured epoxy resin
and the degraded epoxy resin (DER) can be reused to prepare a new resin. Accelerator is commonly employed in the preparation of epoxy resin to expedite the curing process. However
the effect of accelerator content on the re-prepared resin's performance has remained unexplored. Hence
DER is used to replace part bisphenol A diglycidyl ether to prepare new resins with varying accelerator contents
and the comprehensive properties of new resins are investigated. The results demonstrate that the accelerator-free re-prepared resin exhibits a performance that is comparable to that of the original resin. After accelerator is added during the preparation of new resins
the curing temperature of the reconstituted resin shows a decrease
and two peaks appear during the curing exothermic process. Besides
as the accelerator content increases
the insulation performance initially improves and then deteriorates
while the mechanical and thermal properties continue to decline. Through characterisation and chemical simulation analysis
it is believed that excessive accelerators are detrimental to the cross-linking reaction of DER. Therefore
the accelerator content in the new epoxy resin should not be high.
Abstract
Alcoholysis has emerged as a crucial method for the degradation of anhydride-cured epoxy resin
and the degraded epoxy resin (DER) can be reused to prepare a new resin. Accelerator is commonly employed in the preparation of epoxy resin to expedite the curing process. However
the effect of accelerator content on the re-prepared resin's performance has remained unexplored. Hence
DER is used to replace part bisphenol A diglycidyl ether to prepare new resins with varying accelerator contents
and the comprehensive properties of new resins are investigated. The results demonstrate that the accelerator-free re-prepared resin exhibits a performance that is comparable to that of the original resin. After accelerator is added during the preparation of new resins
the curing temperature of the reconstituted resin shows a decrease
and two peaks appear during the curing exothermic process. Besides
as the accelerator content increases
the insulation performance initially improves and then deteriorates
while the mechanical and thermal properties continue to decline. Through characterisation and chemical simulation analysis
it is believed that excessive accelerators are detrimental to the cross-linking reaction of DER. Therefore
the accelerator content in the new epoxy resin should not be high.