Research on Synthesis of Glycidyl Methacrylate

YANG  Xue-Mei; CUI  Yan-Yan; HONG  Peng; DONG  Zhi-Xian; LIU  Xiao-Xuan

English Version Journal Login

您当前的位置：

首页 >

文章列表页 >

Research on Synthesis of Glycidyl Methacrylate

更新时间：2026-05-27

- Research on Synthesis of Glycidyl Methacrylate
- Vol. 27, Issue 4, Pages: 24-27(2010)
- 作者机构：
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Online First：25 December 2010，
  
  Published：2010
- 稿件说明：
移动端阅览
杨雪梅, 崔艳艳, 洪鹏, 董智贤, 刘晓暄. 甲基丙烯酸缩水甘油酯的合成[J]. 广东工业大学学报, 2010, 27(4): 24-27.

YANG Xue-Mei, CUI Yan-Yan, HONG Peng, et al. Research on Synthesis of Glycidyl Methacrylate[J]. 2010, 27(4): 24-27.
杨雪梅, 崔艳艳, 洪鹏, 董智贤, 刘晓暄. 甲基丙烯酸缩水甘油酯的合成[J]. 广东工业大学学报, 2010, 27(4): 24-27. DOI：

YANG Xue-Mei, CUI Yan-Yan, HONG Peng, et al. Research on Synthesis of Glycidyl Methacrylate[J]. 2010, 27(4): 24-27. DOI：

摘要

采用两步法合成甲基丙烯酸缩水甘油酯(GMA)．通过中和反应，由甲基丙烯酸和氢氧化钠反应制得甲基丙烯酸钠盐；经研磨干燥，加入不同的阻聚剂和相转移剂，与环氧氯丙烷(ECH)按一定比例在干燥的反应体系中反应，减压蒸馏后得到产物．结果表明：该反应的最佳阻聚剂为对苯二酚，相转移催化剂为四丁基溴化铵(TBAB)．通过正交实验设计优化了反应条件：反应温度90-95℃ ，反应时问4 h，物料配比W(甲基丙烯酸钠)：W(ECH)=1：6．产率达到86．5% ，用盐酸丙酮法测得环氧值高达98．6% ．

Abstract

Glycidyl methacrylate(GMA)was synthesized through two steps．Firstly，Sodium methacrylate was prepared from methyl acrylic acid and NaOH ，which was ground and dried．With different inhibitors and phase transfer catalysts，GMA was gained by the reaction of Sodium methacrylate and Epichlorohydrin(ECH)with a certain percentage in a dry reaction system and distilled through vacuum distillation．The results show that hydroquinone is the best inhibitor，and phase transfer catalyst is tetra—butylammonium bromide(TBAB)．The optimum reaction conditions are obtained by the orthogonal experimental design：the reaction temperature is 90-95。C．the reaction time is 4 h， (sodium methacrylate)： (ECH)=1：6．Under the given conditions the yield of products can reach 86．5%with purity of98．6% ．

关键词

Keywords

references

高晓蕾，卫冬燕．甲基丙烯酸缩水甘油酯的合成研究[J]，精细与专用化学品，2004，12(21)：15-17.

吕艳萍，李临生．甲基丙烯酸缩水甘油酯的合成研究[J]．精细化工中间体，2004，34(2)：45-50.

姜其斌，周立俊，黄轩．甲基丙烯酸缩水甘油酯的合成研究[J]．应用化工，2003，32(1)：33-35.

张成明，黄岳山，支晓兴，等．Bis．GMA／Nano(SiO，．ZrO，)复合树脂牙科材料的制备[J]．医疗卫生装备，2008，29(9)：1-2.

Isozaki T，Kurokawa M，Ppomma A．Process for preparation of acrylic or mathaerylic acid glycidyl ester by esterifieation of acrylic or mathaerylie acids with epiehlorohydrin：JP，09-59268A2[P]．1997-03-04.

张吉林．甲基丙烯酸缩水甘油酯的合成[J]．河南化工，1998(2)：18-20.

Nishinomiya，Kobe，Takatsuki．Method for producing glycidyl methacrylate：US，5380884[P]．1995-01-10.

梅雪峰，杨玉昆．丙烯酸酯压敏胶粘剂的紫外光交联技术研究[R]．研究报告，2000，21(4)

陈榕珍，成荣明，李国庆，等．UV固化聚丙烯酸醋压敏胶的制备及其性能研究[J]．中国胶粘剂，2006，15(8)：28-30．

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

A Study of Power Quality Regulation Strategies of Energy Storage Converters

Research on Foreign Object Detection in Power Transmission Lines Based on the AAGV-YOLOX Model

The Cross-twin Physics-informed Neural Network for Wave Equations with Conserved Quantities

Bimodal Iterative Cross-attention Fusion Ensemble Framework

A Resource Allocation Optimization Method for Multi-UAV Integrated Sensing, Computing, and Communication Towards Disaster Relief

Related Author

No data

Related Institution

No data

AI问答

⁰