Emission characteristics of aerosol from ammonia-based wet flue gas desulfurization
|更新时间:2025-09-28
|
Emission characteristics of aerosol from ammonia-based wet flue gas desulfurization
Thermal Power GenerationVol. 42, Issue 9, Pages: 32-37(2013)
作者机构:
1. 中石化资产管理公司扬子石化资产分公司
2. 东南大学能源热转换及其过程测控教育部重点实验室
3. 南京师范大学能源与机械工程学院
作者简介:
基金信息:
DOI:
CLC:X513
Published:2013
稿件说明:
移动端阅览
ZHANG Wenwu, SHA Zhiqiang, ZHU Zhongyi, et al. Emission characteristics of aerosol from ammonia-based wet flue gas desulfurization[J]. Thermal power generation, 2013, 42(9): 32-37.
DOI:
ZHANG Wenwu, SHA Zhiqiang, ZHU Zhongyi, et al. Emission characteristics of aerosol from ammonia-based wet flue gas desulfurization[J]. Thermal power generation, 2013, 42(9): 32-37.DOI:
Emission characteristics of aerosol from ammonia-based wet flue gas desulfurization
摘要
结合扬子热电厂二期玛苏莱氨法脱硫工艺运行参数
采用模拟试验装置考察了氨法烟气脱硫工艺的气溶胶排放特性
并对该电厂气溶胶颗粒的来源进行了分析。结果表明:氨法烟气脱硫过程中会产生大量气溶胶颗粒
从数浓度角度而言
主要属亚微米级微粒
但依据质量浓度分布
粒径呈双峰分布
以微米级及大于10μm的颗粒物为主;同时
脱硫前后颗粒物物性发生显著变化
脱硫净烟气中颗粒多呈规则的晶体结构
含长方体、棱柱体等晶习
S、O元素含量显著增加
主要物相成分为(NH4)2SO4;由烟气带出的雾滴经蒸发析出固体微粒是该电厂气溶胶的重要来源。
Abstract
The emission characteristics of aerosols were investigated experimentally during the ammonia-based wet flue gas desulfurization(WFGD)process
according to the practical operation condition of Marsulex ammonia-based desulfurization process of Yangzi Thermal Power Plant.The electrical low pressure impactor(ELPI)
scanning electron microscopy(SEM)and XRD were employed to analyze the aerosol particle size distribution and concentration
morphologies and compositions before and after the desulfurization.The results showed that
agreat amount of aerosol particles were formed during the ammonia-based desulfurization process.A large number of these particles were sub-critical particulate matters
and these aerosol particles of which the mass concentration appeared a bimodal distribution were mainly micro-size or larger than 10μm.Moreover
after the desulfurization
the physical properties of the particles changed significantly.These particles had the smooth surface and regular crystal structure
including cuboid and prismoid crystal habits.Sulfur and oxygen content in these particles increased obviously
and main compound in the particles was ammonium sulfate((NH4)2SO4).The solid fine particles generated by evaporation of droplets brought out by flue gas were the major source of aerosol emitted from the Yangzi Thermal Power Plant.