Thermogravimetric study on combustion characteristics of lignite semicoke
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Thermogravimetric study on combustion characteristics of lignite semicoke
Thermal Power GenerationVol. 42, Issue 11, Pages: 86-92(2013)
作者机构:
1. 浙江大学能源清洁利用国家重点实验室
2. 西安热工研究院有限公司
3. 浙江大学能源清洁利用国家重点实验室
4. 西安热工研究院有限公司
作者简介:
基金信息:
DOI:
CLC:TQ534
Published:2013
稿件说明:
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LIU Jianzhong, LIU Mingqiang, ZHAO Weidong, et al. Thermogravimetric study on combustion characteristics of lignite semicoke[J]. Thermal power generation, 2013, 42(11): 86-92.
DOI:
LIU Jianzhong, LIU Mingqiang, ZHAO Weidong, et al. Thermogravimetric study on combustion characteristics of lignite semicoke[J]. Thermal power generation, 2013, 42(11): 86-92.DOI:
Thermogravimetric study on combustion characteristics of lignite semicoke
The lignite was pyrolyzed in a tube furnace at medium-low temperature between 500℃and 650℃
then the combustion characteristics of the lignite semicoke was analyzed by thermal analysis method.The effects of pyrolysis temperature and holding time on yield
composition and calorific value of the semicoke were investigated.Moreover
the combustion dynamics of the coal samples was studied by the Coats-Redfern integration method
on the basis of the thermogravimetric experiment.The results show that the holding time has no obvious influence on yield
composition
calorific value and combustion characteristics of the lignite semicoke
while the pyrolysis temperature has a great one.After paralysis
the coal rank of the semicoke increased.With an increase in pyrolysis temperature
the C/O ratio
fixed carbon content
ash content and calorific value of semicoke increase
while the yield and volatile content of the semicoke decrease.High temperature makes the combustion characteristics of semicoke be worse and the coal rank tend to be higher.The results indicate that the reaction order model(n=7/6)can be adopted to describe the lignite semicoke combustion.With the increase of pyrolysis temperature and holding time
the reaction reactivity of semicoke decreases while activation energy increases
the activation energy changes within the range from 78.1kJ/mol to 116.4kJ/mol.