Formation mechanism and influencing factors of ammonium bisulfate during the selective catalytic reduction process
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Formation mechanism and influencing factors of ammonium bisulfate during the selective catalytic reduction process
Thermal Power GenerationVol. 43, Issue 2, Pages: 75-78(2014)
作者机构:
华北电力大学环境科学与工程学院
作者简介:
基金信息:
DOI:
CLC:X701
Published:2014
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MA Shuangchen, GUO Meng, SONG Huihui, et al. Formation mechanism and influencing factors of ammonium bisulfate during the selective catalytic reduction process[J]. Thermal power generation, 2014, 43(2): 75-78.
DOI:
MA Shuangchen, GUO Meng, SONG Huihui, et al. Formation mechanism and influencing factors of ammonium bisulfate during the selective catalytic reduction process[J]. Thermal power generation, 2014, 43(2): 75-78.DOI:
Formation mechanism and influencing factors of ammonium bisulfate during the selective catalytic reduction process
The formation mechanism of ammonium bisulfate(ABS)during the flue gas denitrification process was presented.The effect of such parameters as the temperature
ammonia escape amount
SO3concentration
and fly ash on formation of the ABS was investigated.The analysis shows that
formation temperature of ABS is between 190℃and 240℃.The ABS exhibits as gas phase within temperature range from 320℃to 345℃
while it will decompose when the temperature is higher than 345℃.To reduce the formation of ABS
the ammonia escape amount should be reduced by controlling the mole ratio of NH3to NOx within range from 0.8to 1.2
and the oxidation rate of SO2in flue gas should be decreased as much as possible.Aiming at avoiding catalyst clogging and corrosion
it is essential to select the appropriate operation temperature to control the ABS's deposition on catalyst.