Reason analysis for deactivation of commercial SCR de-NOx catalyst and its regeneration
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Reason analysis for deactivation of commercial SCR de-NOx catalyst and its regeneration
Thermal Power GenerationVol. 43, Issue 2, Pages: 109-113(2014)
作者机构:
1. 江西大唐国际抚州发电有限责任公司
2. 华电电力科学研究院
作者简介:
基金信息:
DOI:
CLC:X701
Published:2014
稿件说明:
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YU Xiaowei, ZHOU Yu, LIU Shuai, et al. Reason analysis for deactivation of commercial SCR de-NOx catalyst and its regeneration[J]. Thermal power generation, 2014, 43(2): 109-113.
DOI:
YU Xiaowei, ZHOU Yu, LIU Shuai, et al. Reason analysis for deactivation of commercial SCR de-NOx catalyst and its regeneration[J]. Thermal power generation, 2014, 43(2): 109-113.DOI:
Reason analysis for deactivation of commercial SCR de-NOx catalyst and its regeneration
the denitration efficiency of a commercial SCR catalyst decreased significantly
respectively.Moreover
the one with the shortest operation time had the poorest performance.Thus
the sulfuric acid and ammonia chloride was used to regenerate the catalyst
and such tests as the BET specific surface area
XRD
SEM and EDX were applied to characterize it before and after the regeneration.The results show that
both the H2SO4and NH4Cl had good regeneration effect
and the latter had better one.The denitration efficiency of the regenerated catalyst can reach up to 90%in the lab simulation condition.The active components on surface of the regenerated catalyst had no change and was affected less by space velocity.Due to high temperature
the catalyst with operation time of 14 400hours was deactivated:the nanoparticles on the catalyst surface were seriously sintered and the pore structure was destroyed badly
resulting in nearly no effective recovery by regeneration.