Thermal degradation kinetics of condensate polishing anion exchange resin

YU Yuanchun; ZHOU Baiqing

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Thermal degradation kinetics of condensate polishing anion exchange resin

更新时间：2025-09-28

- Thermal degradation kinetics of condensate polishing anion exchange resin
- Thermal Power Generation Vol. 43, Issue 1, Pages: 61-65(2014)
- 作者机构：
  
  武汉大学动力与机械学院
- 作者简介：
- 基金信息：
- DOI：
  CLC： TM621.8
- Published：2014
- 稿件说明：
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YU Yuanchun, ZHOU Baiqing. Thermal degradation kinetics of condensate polishing anion exchange resin[J]. Thermal power generation, 2014, 43(1): 61-65.
DOI：

YU Yuanchun, ZHOU Baiqing. Thermal degradation kinetics of condensate polishing anion exchange resin[J]. Thermal power generation, 2014, 43(1): 61-65. DOI：

摘要

采用静态浸泡实验研究了3种大孔阴树脂强碱基团降解速率与温度、水料倍率的关系

探讨阴树脂的降解动力学。研究结果表明:不同树脂开始降解的温度不同

阴树脂在60~80℃范围内降解速率明显加快且随着温度升高而增加;在较低的水料倍率下(≤200∶6)

降解反应较好地遵循零级反应动力学;水料倍率会影响阴树脂的降解速率

水料倍率增大

强碱基团降解加速。

Abstract

Factors affecting the thermal degradation rate of anion exchange resin were discussed by static immersion test

such as temperature and water-resin ratio(soak solution and resin quality ratio).The results showed that

the degradation reaction followed the zero-order kinetics well when the water-resin ratio was not higher than 200∶6within temperature range from 60 ℃to 80℃.Strong-base loss rate increased with the temperature and water-resin ratio.In addition

static immersion test should try to eliminate the effect of water-resin ratio

which will make the heat resistance results reflect and guide the actual production better.

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Related Institution

Electric Power Research Institute of Guangdong Power Grid Co.,Ltd.

School of Energy Power and Mechanical Engineering, North China Electric Power University

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内蒙古工业大学能源与动力工程学院

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