Isothermal steam gasification characteristics of Yining coal char in a fixed bed reactor
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Isothermal steam gasification characteristics of Yining coal char in a fixed bed reactor
Thermal Power GenerationVol. 43, Issue 4, Pages: 63-68(2014)
作者机构:
1. 华北电力大学能源动力与机械工程学院
2. 宁夏电力公司教育培训中心
作者简介:
基金信息:
DOI:
CLC:TK21
Published:2014
稿件说明:
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CHEN Hongwei, YAN Jingbo, ZHANG Meiyou, et al. Isothermal steam gasification characteristics of Yining coal char in a fixed bed reactor[J]. Thermal power generation, 2014, 43(4): 63-68.
DOI:
CHEN Hongwei, YAN Jingbo, ZHANG Meiyou, et al. Isothermal steam gasification characteristics of Yining coal char in a fixed bed reactor[J]. Thermal power generation, 2014, 43(4): 63-68.DOI:
Isothermal steam gasification characteristics of Yining coal char in a fixed bed reactor
摘要
研究了水蒸气分压、热解温度、热解恒温时间和气化温度对伊宁煤焦水蒸气气化反应的影响
并获得了相关动力学参数。结果表明:随着水蒸气分压的提高
煤焦气化活性提高
水蒸气分压大于0.045MPa时
煤焦表面活性位已经达到饱和;提高热解温度、延长恒温时间均会使煤焦气化活性降低
随着气化温度的升高
热解温度、恒温时间对煤焦气化活性的影响减小;气化温度是影响煤焦气化活性的主要因素
升高气化温度能明显提高煤焦气化活性;收缩核模型能够较好地描述伊宁煤水蒸气气化
由该模型求出的活化能范围为148.2~189.6kJ/mol。
Abstract
The effects of steam partial pressure
pyrolysis temperature
coke-forming time and gasification temperature on steam gasification of Yining coal char were studied
and a dynamic model was established for the gasification reaction.The results show that
the gasification reaction activity of char increases with the steam partial pressure(when the steam partial pressure is greater than 0.045MPa
the active sites on char have reached saturation)
while rising the pyrolysis temperature and prolonging the constant temperature time can both reduce the gasification reaction activity of char.With the increasing gasification temperature
the influence of pyrolysis temperature and coke-forming time on the steam gasification decreases.The gasification temperature is the main factor affecting the gasification activity of char.Rising the gasification temperature can enhance the gasification reactivity significantly.The activation energy obtained by the shrinking core model ranges from 148.2kJ/mol to 189.6kJ/mol
which can describe the steam gasification of Yining coal.