Thermogravimetric experiments and dynamic analysis on spontaneous combustion characteristics of lignite
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Thermogravimetric experiments and dynamic analysis on spontaneous combustion characteristics of lignite
Thermal Power GenerationVol. 43, Issue 6, Pages: 71-76(2014)
作者机构:
1. 浙江大学能源清洁利用国家重点实验室
2. 西安热工研究院有限公司
3. 浙江大学能源清洁利用国家重点实验室
4. 西安热工研究院有限公司
作者简介:
基金信息:
DOI:
CLC:TQ534
Published:2014
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ZHANG Bin, LIU Jianzhong, ZHAO Weidong, et al. Thermogravimetric experiments and dynamic analysis on spontaneous combustion characteristics of lignite[J]. Thermal power generation, 2014, 43(6): 71-76.
DOI:
ZHANG Bin, LIU Jianzhong, ZHAO Weidong, et al. Thermogravimetric experiments and dynamic analysis on spontaneous combustion characteristics of lignite[J]. Thermal power generation, 2014, 43(6): 71-76.DOI:
Thermogravimetric experiments and dynamic analysis on spontaneous combustion characteristics of lignite
Thermogravimetric experiments on Ximeng lignite and Indonesia lignite were carried out
and the results were compared with that of the Datong bituminous coal
Pingdingshan bituminous coal
Shenhua low ash bituminous coal and Yangquan anthracite.By analyzing the TG and DTG curves
the whole process from coal oxidation to coal combustion could be divided into six stages:physical adsorption
water evaporation with losing weight
absorption of oxygen with increasing weight
thermal decomposition
combustion and burning out.The characteristic temperatures of each stage were obtained.The results show that
the tendency of spontaneous combustion of the above two lignite was significantly obvious than that of the other four bituminous coal and anthracite.Coats-Redfern integral method was used to analyze the samples' oxidative combustion dynamic characteristics.Moreover
activation energy of the six coal samples was calculated to analyze the tendency of spontaneous combustion of coal.The calculation results show that
the oxidation process of the six coal samples belonged to the first-order reaction
and the tendency of spontaneous combustion of the two lignite coal was greater.The tendency of spontaneous combustion of Ximeng lignite was affected by particle size and oxygen density.Analysis shows that:the smaller the particle size
the stronger the tendency of spontaneous combustion;the greater the oxygen density
the stronger the tendency of spontaneous combustion in general.