Co-combustion of biomass straw and bituminous coal:characteristics and kinetics study
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Co-combustion of biomass straw and bituminous coal:characteristics and kinetics study
Thermal Power GenerationVol. 43, Issue 8, Pages: 52-59(2014)
作者机构:
广东石油化工学院机电工程学院
作者简介:
基金信息:
DOI:
CLC:TK6;TK16
Published:2014
稿件说明:
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TIAN Hong, LIAO Zhengzhu. Co-combustion of biomass straw and bituminous coal:characteristics and kinetics study[J]. Thermal power generation, 2014, 43(8): 52-59.
DOI:
TIAN Hong, LIAO Zhengzhu. Co-combustion of biomass straw and bituminous coal:characteristics and kinetics study[J]. Thermal power generation, 2014, 43(8): 52-59.DOI:
Co-combustion of biomass straw and bituminous coal:characteristics and kinetics study
摘要
采用TG-DTG-DSC联用技术对农业生物质稻草、烟煤及其混合燃料进行了热重实验
研究了其可燃特性、着火特性、燃尽特性及综合燃烧特性
分析了混合燃料的燃烧机理
并计算了燃烧动力学参数。结果表明:稻草与烟煤混烧的DTG曲线出现2个峰值
随着稻草在混合燃料中所占比例的增加
在DTG曲线2个峰值之间
DSC曲线逐渐出现向上的吸热峰;混合试样的着火温度大大低于烟煤的着火温度
混合燃料S6(稻草∶烟煤=4∶1)的着火温度及燃尽温度最低
其最大反应速度和平均反应速度均大于其他混合燃料的值;混合燃料的前期主要属于均相着火
后期属于多相着火;混合燃料在低温阶段反应级数约为1.5
高温阶段反应级数约为0.4;混合燃料低温阶段活化能及频率因子均大于高温阶段的活化能及频率因子
体现了活化能与频率因子变化的一致性;在烟煤中适当加入生物质稻草有利于促进烟煤的充分燃烧
提高其燃烧效率
从而降低纯烧煤所带来的环境污染。
Abstract
In order to take full use of the agricultural biomass straw and bituminous coal
the thermogravimetric-differential thermogravimetric-differential scanning calorimetry(TG-DTG-DSC)thermal analysis technology was employed to conduct thermogravimetric experiment on straw
bituminous coal and their mixtures.The combustible characteristics
ignition performance
burnout feature and comprehensive combustion characteristics of the fuels were investigated.Moreover
the combustion mechanism of the mixed fuel was analyzed
and kinetics parameters of the combustion were calculated.The results show that
DTG curves of the mixture of straw and bituminous coal appeared two peaks.With an increase in the proportion of straw in the mixture
an upward endothermic peak gradually appeared on the DSC curve
between the two peaks on the DTG curves.The ignition temperature of the mixed sample was much lower than that of the bituminous coal.The mixture S6 had the lowest ignition temperature and burnout temperature.Its maximum and average reaction speed was higher than that of other mixtures.The combustible characteristics index
ignition performance index
burnout feature index and comprehensive combustion characteristics index of S6 were much higher than that of other mixed fuels and the bituminous coal.Furthermore
these indexes of S6 increased with the proportion of straw.The early burning stage of the mixed fuels was mainly homogeneous ignition
while the late stage was multiphase ignition.The reaction order of the mixed fuels at low/high temperature was about 1.5/0.4.The reaction activation energy and frequency factor at low temperature were larger than that at high temperature
reflecting consistency of variation of the activation energy and frequency factor.Properly adding biomass straw was beneficial to promoting full combustion of the bituminous coal
which will improve the combustion efficiency and reduce the net environmental pollution.