Mechanism research on catalyst attrition in SCR denitration system and the treatment
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Mechanism research on catalyst attrition in SCR denitration system and the treatment
Thermal Power GenerationVol. 44, Issue 12, Pages: 119-125(2015)
作者机构:
中国大唐集团科学技术研究院有限公司华中分公司
作者简介:
基金信息:
DOI:
CLC:X773
Published:2015
稿件说明:
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AN Jingxue, WANG Lei, QIN Qi, et al. Mechanism research on catalyst attrition in SCR denitration system and the treatment[J]. Thermal power generation, 2015, 44(12): 119-125.
DOI:
AN Jingxue, WANG Lei, QIN Qi, et al. Mechanism research on catalyst attrition in SCR denitration system and the treatment[J]. Thermal power generation, 2015, 44(12): 119-125.DOI:
Mechanism research on catalyst attrition in SCR denitration system and the treatment
摘要
国内某超超临界660 MW机组直流锅炉脱硝系统选择性催化还原(SCR)催化剂出现严重磨损
导致脱硝装置失效
经检查发现磨损区域集中于催化剂的近锅炉侧。结合数值模拟及现场试验数据
分析得出催化剂局部磨损的形成机理是烟道内飞灰质量浓度分布不均匀
造成飞灰颗粒富集在催化剂近锅炉侧
长期冲刷催化剂局部。通过调整型烟道水平段第1组导流板位置、减少导流板的数量并增加撞击式导流装置后
SCR装置内型烟道水平段和催化剂上部竖直烟道的烟气流场及飞灰颗粒场的分布更加均匀
型烟道水平段飞灰质量浓度相对均方根由优化前的0.331减至0.241
有效解决了SCR催化剂局部严重磨损问题。
Abstract
Serious catalyst attrition occurred in selective catalytic reduction(SCR)system of a domestic ultra-supercritical 660 MW unit once-through boiler
leading to the failure of the SCR device.Statistics shows the attrition area focused on near side of the boiler.Combined with the numerical simulation and testing data
the formation mechanism of the catalyst attrition was analyzed and the major reason is that the uneven distribution of fly ash causes the fly ash particles concentrate at the near side of the boiler and scour the catalyst's local area for a long time.Through regulating the positions of the Group I guidance plates at the horizontalπ-type flue duct
reducing the guiding plate number and increasing aguiding percussion device
the diffusion performance of the ash particles at the horizontalπ-type flue duct was improved.The relative root-mean-square of mass concentration of the fly ash at the horizontalπ-type flue duct decreased from0.331 to 0.241
resulting in a more even distribution of flue gas flow field and fly ash particle field at the horizontalπ-type flue duct and the vertical flue duct at top of the catalysts.Thus
the serious catalyst attrition problem was solved.