Corrosion behavior of chlorine ions under all volatile treatment conditions of subcritical drum boilers
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Corrosion behavior of chlorine ions under all volatile treatment conditions of subcritical drum boilers
Thermal Power GenerationVol. 45, Issue 3, Pages: 82-86(2016)
作者机构:
西安热工研究院有限公司
作者简介:
基金信息:
DOI:
CLC:TM621.8
Published:2016
稿件说明:
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SONG Fei, SUN Hao, TIAN Li, et al. Corrosion behavior of chlorine ions under all volatile treatment conditions of subcritical drum boilers[J]. Thermal power generation, 2016, 45(3): 82-86.
DOI:
SONG Fei, SUN Hao, TIAN Li, et al. Corrosion behavior of chlorine ions under all volatile treatment conditions of subcritical drum boilers[J]. Thermal power generation, 2016, 45(3): 82-86.DOI:
Corrosion behavior of chlorine ions under all volatile treatment conditions of subcritical drum boilers
摘要
模拟亚临界汽包炉全挥发处理(AVT)环境
在高温无氧碱性条件下
采用电化学和试片表面金相分析方法
对氯离子(Cl-)在水冷壁管内表面(向火侧)发生浓缩时的腐蚀情况
包括不同Cl-质量浓度对金属表面钝态膜的影响
进行了研究。结果表明:当Cl-质量浓度≤3.00mg/L时
金属膜电阻较大
金属膜完整;当Cl-质量浓度3.00mg/L时
金属膜电阻急剧减小
金属表面出现点蚀
且随Cl-质量浓度增大
金属表面腐蚀加重。
Abstract
Under all volatile treatment(AVT)working conditions of subcritical drum boiler
in high temperature anaerobic alkaline environment
the effect of Cl-on passive film on metal surface when Cl-was concentrated in the inner surface of the wall tube(the side facing the fire)was investigated
by electrochemical online test and the surface topography images.The results show that
when the Cl-concentration is equal or lower than 3.00mg/L
the metal film resistance is large and the metal film is complete.While when the Cl-concentration is higher than 3.00mg/L
the metal film resistance drops sharply
and pitting corrosion occurs on the metal surface.Moreover
the corrosion on the metal surface gets severe with the increasing Cl-concentration.