Several Important Issues and Thinking About Engineering Dielectrics
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Several Important Issues and Thinking About Engineering Dielectrics
Vol. 41, Issue 8, Pages: 2473-2480(2015)
作者机构:
1. 青岛科技大学材料科学与工程学院
2. 西安交通大学电力设备电气绝缘国家重点实验室
3. 清华大学电力系统及发电设备控制和仿真国家重点实验室
4. 哈尔滨理工大学电气与电子工程学院
作者简介:
基金信息:
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Published Online:31 August 2015,
Published:2015
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LEI Qingquan, LI Shengtao. Several Important Issues and Thinking About Engineering Dielectrics[J]. 2015, 41(8): 2473-2480.
DOI:
LEI Qingquan, LI Shengtao. Several Important Issues and Thinking About Engineering Dielectrics[J]. 2015, 41(8): 2473-2480.DOI:
Several Important Issues and Thinking About Engineering Dielectrics
摘要
随着工程电介质领域研究的发展
诸多没有得到公认解释的问题逐渐出现
为此
本文提出了几个重要的问题及思考以供相关研究工作者参考。1994年Lewis首次提出了纳米电介质
2003年至今已成为工程电介质领域的研究热点
但从20余年该领域的研究内容、作者的原意以及新近又提出的纳米结构电介质来看
我们认为应把名称改为纳米电介质复合物
并按照低维物理对纳米电介质作了重新定义。分析了Lewis与Tanaka界面的具体含义
提出了纳米高聚物复合物硬/软界面及其具有结构复杂性、不确定性与易变性的新概念
并剖析了硬、软表面的尺度及理化特性。提出了从A Einstein还原论、P W Anderson的层展现象与R P Feynmann的思维方法以启迪相关研究的新思维。从空间电荷限制电流(SCLC)存在条件的约束和高聚物或其复合物中由于自身结构的多层次性、复杂界面、电极接触以及共存的电子与离子电导等因素的严重影响
With the development of studies in engineering dielectrics
more and more unaccepted questions arise. To provide peer reviews for these questions
we propose several important issues and thinking. The concept of nanometric dielectrics was firstly proposed by T J Lewis in 1994
and it has become the research focus of engineering dielectrics since 2003. However
from the point of view of the research results for more than 20 years
the original intention of the author and some recently-proposed nanostructured dielectrics
we believe that nanometric dielectrics should be renamed nanodielectric composites
and be redefined in accordance with low dimensional physics. The specific meaning of Lewis interface and Tanaka interface is analyzed
hard/soft interface of nano polymeric composites is proposed
new concepts of structural complexity
uncertainty and mutability are described
and the scale and physical and chemical properties of hard and soft surfaces are analyzed. New thoughts are inspired from the perspective of Einstein reductionism
emergent phenomena of P W Anderson
and scientific prediction of R P Feynmann. Constraints of existent conditions of space charge limited current(SCLC) are studied
and hierarchical levels of its self-structure
complex interface
electrode contact
concomitant electronic and ionic conductivity and other factors in polymers or their composites have serious impacts on SCLC. It is proposed that SCLC is not solely determined by carriers which are the same as injected carriers in the transition from ohmic region to high field region
i e.
electrode injection SCLC region. In particular
the contribution of ionic conductivity to the current in low and high field region is of close scrutiny when measurement conditions are determined. Therefore
the main features and distinction methods of ionic and electronic conductivity are listed. In view of pulse related space charge measurement methods
especially pulsed electroacoustic(PEA) method has been mainly adopted in the world
advantages and disadvantages of PEA
and the method for verifying the accuracy and repeatability of measurement results are proposed. According to the features of polymer structure
a pressure stimulated current(PSC) device should be built up for distinguishing space charges derived from concentration gradient of electrons
ions
and dipoles to compensate the serious shortcomings of PEA measurements.