Effect of Silicon Dioxide Nano-filler on Dielectric and Space Charge Properties of Epoxy Resin
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Effect of Silicon Dioxide Nano-filler on Dielectric and Space Charge Properties of Epoxy Resin
Vol. 44, Issue 6, Pages: 1870-1877(2018)
作者机构:
太原理工大学电气与动力工程学院煤矿装备与安全控制山西省重点实验室
作者简介:
基金信息:
DOI:
CLC:
Published Online:10 July 2018,
Published:2018
稿件说明:
移动端阅览
LI Yuanyuan, TIAN Muqin, LEI Zhipeng, et al. Effect of Silicon Dioxide Nano-filler on Dielectric and Space Charge Properties of Epoxy Resin[J]. 2018, 44(6): 1870-1877.
DOI:
LI Yuanyuan, TIAN Muqin, LEI Zhipeng, et al. Effect of Silicon Dioxide Nano-filler on Dielectric and Space Charge Properties of Epoxy Resin[J]. 2018, 44(6): 1870-1877.DOI:
Effect of Silicon Dioxide Nano-filler on Dielectric and Space Charge Properties of Epoxy Resin
摘要
为研究纳米颗粒对环氧树脂(epoxy resin
ER)介电和空间电荷特性的影响
以环氧树脂为基体材料
纳米二氧化硅(silicon dioxide
SiO
2
)为填料
制备了SiO
2
纳米颗粒质量分数在0~5%范围内的ER/SiO
2
纳米复合电介质。测试和研究了复合电介质在不同频率下的介电特性和直流场强为33 k V/mm下的空间电荷行为。当SiO
2
纳米颗粒的质量分数为0.5%和1%时
复合电介质可以获得较低的介电常数和介质损耗
同时有效抑制了同极性空间电荷在电极界面处的积累及注入;当SiO
2
纳米颗粒的质量分数为2.5%和5%时
复合电介质在低频区域介电常数和介质损耗均比纯环氧树脂高
但在高频区域变化不明显
同时在电极界面处的空间电荷积累显著增加、注入明显。研究结果表明:纳米颗粒含量较低时ER/SiO
2
复合电介质介电和空间电荷性能得到提高
是由于受到环氧树脂基体和纳米粒子之间的界面区影响
界面区是改善环氧树脂纳米复合材料电性能的关键因素。
Abstract
The effect of nanoparticles on the dielectric and spatial charge properties of epoxy resin was studied. The epoxy resin nanodielectrics with different contents of nano-silicon dioxide(SiO
2
) from 0%~5% were prepared by using epoxy resin as a base material and SiO
2
as a filler. The dielectric permittivity and dissipation factor depending on frequency in the range from 0.01 Hz to 1 MHz were studied. The space charge behaviors of samples were also observed under dc electric field of 33 kV/mm. When the SiO
2
concentrations are 0.5% and 1%
ER/SiO
2
nanodielectrics have lower relative permittivity and dissipation factor compared to neat
ER
in the meantime
the accumulation and injection of homocharge were effectively suppressed at the electrode interface. When the SiO
2
concentrations are 2.5% and 5%
ER/SiO
2
nanodielectrics have higher relative permittivity and dissipation factor compared to neat ER in the low frequency region
but the change is not obvious in the high-frequency region. At the same time
the space charge accumulation and the injection at the electrode interface increase significantly. The results indicate that the presence of nanoparticles strongly enhances the dielectric and space charge properties of the epoxy resin
which is influenced by the interfacial region between epoxy and nanoparticles. The interfacial region is the key factor in affecting the electrical performances of ER/SiO