Infrared Absorption Characteristics of Decomposition Products COF2 and N2O of SF6/N2 Gas Mixtures
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Infrared Absorption Characteristics of Decomposition Products COF2 and N2O of SF6/N2 Gas Mixtures
Vol. 46, Issue 8, Pages: 2890-2896(2020)
作者机构:
1. 中国科学院电工研究所
2. 中国科学院大学
3. 国网安徽省电力有限公司电力科学研究院
作者简介:
基金信息:
DOI:
CLC:
Published Online:31 August 2020,
Published:2020
稿件说明:
移动端阅览
QIU Zongjia, LI Kang, WAN Liujie, et al. Infrared Absorption Characteristics of Decomposition Products COF2 and N2O of SF6/N2 Gas Mixtures[J]. 2020, 46(8): 2890-2896.
DOI:
QIU Zongjia, LI Kang, WAN Liujie, et al. Infrared Absorption Characteristics of Decomposition Products COF2 and N2O of SF6/N2 Gas Mixtures[J]. 2020, 46(8): 2890-2896.DOI:
Infrared Absorption Characteristics of Decomposition Products COF2 and N2O of SF6/N2 Gas Mixtures
摘要
目前SF
6
/N
2
混合气体作为SF
6
气体的替代气体已应用于许多电力设备中
而检测这些电气设备发生故障后生成的COF
2
、N
2
O等新分解气体有助于开展电气设备的故障诊断。为研究基于红外吸收特性的SF
6
/N
2
混合气体典型分解气体的检测技术
利用HITRAN数据库给出的吸收谱线强度、线型函数等参数
对典型组分COF
2
、N
2
O的红外吸收特性进行研究;得到了COF
2
在波数400~2 000 cm
-1
和N
2
O在波数400~8 000 cm
-1
范围内的红外吸收谱段、最强吸收处的中心波长、吸收系数峰值;并分析了压强和温度对COF
2
、N
2
O的强吸收谱的影响。结果表明:这2种分解气体在红外热辐射光源有效谱段1.2~10μm内具有较强吸收
可以用基于红外热辐射光源的光声光谱装置进行检测;且气体吸收谱线的吸收系数随压强的增大而增大
但不同气体增大程度不同;随温度的升高气体主要吸收谱段的峰值吸收系数减小
但也有部分吸收谱段交叠处的峰值吸收系数增大;COF
2
、N
2
O在运行条件(505 kPa
温度313 K)下的红外吸收系数大于标准条件(101 kPa
温度296 K)下
运行条件更利于气体检测。
Abstract
SF
6
/N
2
mixed gas as the substitute for SF
6
gas has been applied in many power devices. Detecting new generated decomposition gases such as COF
2
and N
2
O after failure of electrical equipment is useful to the fault diagnosis of electrical equipments. In order to study typical decomposition gases detection technology of SF
6
/N
2
mixed gas based on infrared absorption characteristics
the parameters of absorption line intensity and linear function given by HITRAN database for the above-mentioned typical components COF
2
and N
2
O are used. The infrared absorption spectrum
the central wavelength and the peak value of the absorption coefficient of COF
2
in the range of 400~2 000 cm
-1
and N
2
O in the range of 400~8 000 cm
-1
are obtained. At the same time
the effects of pressure and temperature on the absorption of COF
2
and N
2
O are analyzed. The results show that these two kinds of decomposition gases have strong absorption in the effective spectrum of infrared thermal radiation source in 1.2~10 μm
and can be detected by photoacoustic spectroscopy device based on infrared thermal radiation source. Meanwhile the absorption coefficient of the gas absorption line increases with the increase of pressure
but different gases increase in different degrees. As the temperature increases
the peak absorption coefficient of most absorption lines of the gas decreases
while a few absorption lines increase. The infrared absorption coefficient of COF
2
and N
2
O at operating conditions(pressure of 505 kPa
temperature 313 K) is greater than that at standard conditions(pressure 101 kPa
temperature 296 K)
and operating conditions are favourable for gas detection.