毕冬雪, 李雅轩, 肖雨亭, 陆金丰, 路光杰, 何发泉. 废SCR脱硝催化剂再生与金属回收及载体回用技术[J]. 电力科技与环保, 2022, 38(3): 232-237. DOI: 10.19944/j.eptep.1674-8069.2022.03.010
引用本文: 毕冬雪, 李雅轩, 肖雨亭, 陆金丰, 路光杰, 何发泉. 废SCR脱硝催化剂再生与金属回收及载体回用技术[J]. 电力科技与环保, 2022, 38(3): 232-237. DOI: 10.19944/j.eptep.1674-8069.2022.03.010
BI Dongxue, LI Yaxuan, XIAO Yuting, LU Jinfeng, LU Guangjie, HE Faquan. Waste SCR denitration catalyst regeneration and metal recovery and carrier reuse technology[J]. Electric Power Technology and Environmental Protection, 2022, 38(3): 232-237. DOI: 10.19944/j.eptep.1674-8069.2022.03.010
Citation: BI Dongxue, LI Yaxuan, XIAO Yuting, LU Jinfeng, LU Guangjie, HE Faquan. Waste SCR denitration catalyst regeneration and metal recovery and carrier reuse technology[J]. Electric Power Technology and Environmental Protection, 2022, 38(3): 232-237. DOI: 10.19944/j.eptep.1674-8069.2022.03.010

废SCR脱硝催化剂再生与金属回收及载体回用技术

Waste SCR denitration catalyst regeneration and metal recovery and carrier reuse technology

  • 摘要: 为实现我国燃煤锅炉烟气中氮氧化物(NOx)的超低排放,选择性催化还原(SCR)技术被大量推广应用。SCR技术的关键在于脱硝催化剂的性能,脱硝催化剂在使用过程中由于物理结构损坏和化学中毒导致催化剂失活。随着SCR技术推广而产生的废脱硝催化剂量大幅度增加,面临着带来环境污染风险和资源浪费问题。基于废脱硝催化剂主要成分锐钛型TiO2、钨、钒与新催化剂一致,循环回用至新催化剂制备是必然的发展趋势。废脱硝催化剂的回收利用主要分直接再生回用、有价金属回收和载体回用三类。直接再生回用针对的是结构完好的废脱硝催化剂,可采用空气吹扫、清水冲洗、化学药剂清洗、活性植入、高温焙烧等工艺处理。我国废脱硝催化剂的结构破损率超过50%,大部分无法直接再生回用,可采取酸碱主导工艺、熔融技术从破损的废脱硝催化剂中回收V、W、Ti等有价金属。因此,需要加快研究可行的载体回用技术,创建基于脱硝催化剂载体孔结构劣化指数的载体重构技术判定标准,揭示载体深度净化和重构机理,形成经济合理的废弃环保催化剂无害化、资源化成套技术。以资源绿色循环利用为目标,根据废SCR脱硝催化剂的品质设计适宜的技术路线和生产工艺。未来可通过对废SCR脱硝催化剂再生全生命周期运行管理和催化剂产品在长期运行中的特征表现及运行深入探究,完善工艺、加强回收利用效率和降低生产能耗,解决再生载体催化剂可靠性的难题。

     

    Abstract: In order to achieve the ultra-low emission of nitrogen oxides and NOx in coal-fired boilers in our country, selective catalytic reduction(SCR) denitrification technology has been widely promoted and applied in China. The key to SCR denitrification technology lies in the performance of SCR denitrification catalyst. The SCR catalyst are can be deactivated due to physical structure damage and chemical poisoning during use. The large amount of waste SCR catalyst produced faces the problem of environmental pollution risks and resource waste. Based on the fact that the main components of the waste denitration catalyst, anatase TiO2, W, and V are consistent with the new catalyst, it is an inevitable development trend to recycle and reuse the new catalyst. The recycling and utilization of waste denitration catalysts are mainly divided into three categories: direct regeneration and recycling, valuable metal recycling and carrier recycling. For the spent denitration catalyst with intact structure, it can be directly regenerated and reused by air purging, water washing, chemical cleaning, active implantation, high temperature roasting and other processes. The structural damage rate of waste denitration catalysts in our country exceeds 50%. Most of them cannot be directly regenerated and reused. Valuable metals such as V, W, and Ti can be recovered from damaged waste denitration catalysts by adopting acid-base leading process and melting technology. Therefore, it is necessary to speed up the research on feasible carrier reuse technology, create a carrier reconstruction technology judgment standard based on the degradation index of the pore structure of the denitration catalyst carrier, reveal the deep purification and reconstruction mechanism of the carrier, and form an economical and re asonable waste environmental protection catalyst. With the goal of green recycling of resources,appropriate technical routes and production processes are designed according to the quality of waste SCR denitration catalysts. Through the full life cycle operation management of the regeneration of spent SCR denitrification catalysts and the characteristic performance and operation of catalyst products in long-term operation,the process can be improved. The efficiency of recycling and utilization and the reduction of production energy consumption can solve the problem of the reliability of the regenerated carrier catalyst.

     

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