刘军, 汪瑞平, 宫恩蒙. 基于烟气再循环的循环流化床锅炉SNCR-SCR联合脱硝系统设计[J]. 电力学报, 2022, 37(4): 318-323. DOI: 10.13357/j.dlxb.2022.040
引用本文: 刘军, 汪瑞平, 宫恩蒙. 基于烟气再循环的循环流化床锅炉SNCR-SCR联合脱硝系统设计[J]. 电力学报, 2022, 37(4): 318-323. DOI: 10.13357/j.dlxb.2022.040
LIU Jun, WANG Rui-ping, GONG En-meng. Design of SNCR-SCR Combined Denitrification System for Circulating Fluidized Bed Boiler Based on Flue Gas Recirculation[J]. Journal of Electric Power, 2022, 37(4): 318-323. DOI: 10.13357/j.dlxb.2022.040
Citation: LIU Jun, WANG Rui-ping, GONG En-meng. Design of SNCR-SCR Combined Denitrification System for Circulating Fluidized Bed Boiler Based on Flue Gas Recirculation[J]. Journal of Electric Power, 2022, 37(4): 318-323. DOI: 10.13357/j.dlxb.2022.040

基于烟气再循环的循环流化床锅炉SNCR-SCR联合脱硝系统设计

Design of SNCR-SCR Combined Denitrification System for Circulating Fluidized Bed Boiler Based on Flue Gas Recirculation

  • 摘要: 循环流化床(CFB)锅炉烟气脱硝技术普遍采用选择性非催化还原法(SNCR)。一般在 50%~100% 负荷工况下,SNCR 可实现锅炉 NOx超低排放。通过对某 350 MW CFB 锅炉不同负荷工况下 NOx排放浓度进行摸底试验和分析,当机组负荷在 175 MW 时,旋风分离器入口温度约 750 ℃;当机组负荷在 105 MW 时,旋风分离器入口温度仅约 640 ℃,SNCR 脱硝反应效率大幅度降低,NOx排放超标,氨逃逸浓度较高。为了实现该锅炉在 50% 以下负荷时 NOx达标排放,进行了脱硝方案的设计和改造,设计了基于烟气再循环的 SNCR-SCR 脱硝系统,利用检修工期分两步实施改造,并在第一步完成 SCR 脱销系统改造时进行深度调峰试验。深度调峰试验表明,100%、75% 和50% 负荷下的脱硝效率较改造前分别提高 4. 27%、2. 65% 和 5. 70%;30% 负荷下的脱硝效率较改造前提高了 50%以上。改造后,在 30%~50% 负荷下的锅炉 NOx达标排放,氨逃逸率大幅降低,并遏制了改造前空预器堵灰问题。采用该脱销方案可实现机组 30%~100% 负荷下 NOx达标排放,为机组能够参与深度调峰提供了保障,为企业实现了较大的经济效益和社会效益。

     

    Abstract: Selective non-catalytic reduction(SNCR)is widely used in flue gas denitration technology of circulating fluidized bed(CFB)boiler. Generally,under 50%~100% load conditions,SNCR can achieve ultra-low NOxemission requirements of boilers. The NOxemission concentration of a 350 MW CFB boiler under different load conditions was tested and analyzed. When the unit load was 175 MW,the inlet temperature of cyclone separator was about 750 ℃. When the unit load is 105 MW,the inlet temperature of the cyclone separator is only about 640 ℃,and the reaction efficiency of SNCR denitrification is greatly reduced,NOxemission and ammonia escape rate exceed the standard. In order to achieve the standard emission of NOxwhen the boiler is under 50%of the load,the denitrification scheme is designed and transformed,and the transformation scheme is determined as flue Gas Recirculation+SNCR-SCR denitrification technology. The transformation is implemented in two steps according to the maintenance period, and the deep peak shaving test is carried out when the SCR selling system transformation is completed in the first step. The deep peak shaving test after the transformation shows that the denitrification efficiency under 100%,75% and 50% load is increased by 4. 27%,2. 65% and5. 70% respectively compared with that before modification. The denitrification efficiency under 30% load is more than 50% higher than that before transformation. After the transformation,the boiler NOxemission under30%~50% load is up to standard,ammonia escape rate is greatly reduced,and the ash blocking problem of the air preheater before the transformation is alleviated. The standard emission of NOxunder 30%~100% load of the unit can be achieved by the denitration scheme,which can provide guarantee for the unit to participate in the deep peak shaving, and realize great economic and social benefits for the enterprise..

     

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