孙明辉, 刘少军, 周丹娜, 宋亮亮, 李春京. Pt/air电化学氧泵在450℃铅铋合金中的控氧特性研究[J]. 核科学与工程, 2023, 43(3): 637-644.
引用本文: 孙明辉, 刘少军, 周丹娜, 宋亮亮, 李春京. Pt/air电化学氧泵在450℃铅铋合金中的控氧特性研究[J]. 核科学与工程, 2023, 43(3): 637-644.
SUN Minghui, LIU Shaojun, ZHOU Danna, SONG Liangliang, LI Chunjing. Oxygen Control Characteristics of Pt/air Electrochemical Oxygen Pump in Lead-bismuth Alloy at 450℃[J]. Chinese Journal of Nuclear Science and Engineering, 2023, 43(3): 637-644.
Citation: SUN Minghui, LIU Shaojun, ZHOU Danna, SONG Liangliang, LI Chunjing. Oxygen Control Characteristics of Pt/air Electrochemical Oxygen Pump in Lead-bismuth Alloy at 450℃[J]. Chinese Journal of Nuclear Science and Engineering, 2023, 43(3): 637-644.

Pt/air电化学氧泵在450℃铅铋合金中的控氧特性研究

Oxygen Control Characteristics of Pt/air Electrochemical Oxygen Pump in Lead-bismuth Alloy at 450℃

  • 摘要: 铅铋共晶合金(LeadBismuthEutectic,LBE)氧含量调控直接影响结构材料的铅铋腐蚀性能。气相氧控容易产生放射性气体,固相氧控氧化铅原料则难以在线更换补充,因此国际上发展了电化学氧泵(Electrochemical Oxygen Pump,EOP)控氧方法。本论文采用工艺成熟、高还原催化活性的Pt研制了一种新型的Pt/air型电化学氧泵,并利用电流-时间法在静态LBE实验装置中开展了电化学氧泵的控氧测氧研究。研究结果表明Pt/air型电化学氧泵可以有效调控LBE氧浓度,且氧在液态LBE中的传质扩散可能会影响氧泵除氧效率。

     

    Abstract: The corrosion performance of structural materials is directly affected by the control of oxygen content in the lead-bismuth eutectic alloy(LBE). Gas-phase oxygen control may generate gaseous radioactive waste, and solid PbO raw materials for solid-phase oxygen control might be hard to replenish online. Therefore, an electrochemical oxygen pump(EOP)oxygen control method has been developed internationally. In this paper, the Pt/air EOP was fabricated using Pt with mature technology and high reduction catalytic activity, and the oxygen control and measurement of EOP was studied by the current-time method in the static lead-bismuth experimental device. The results show that the oxygen content of LBE can be effectively control by Pt/air EOP, and the deoxidation efficiency of the oxygen pump might be limited by the mass transfer of oxygen in the LBE.

     

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