MA Shuangchen, JIN Xin, SUN Yunxue, et al. THE FORMATION MECHANISM OF AMMONIUM BISULFATE IN SCR FLUE GAS DENITRIFICATION PROCESS AND CONTROL THEREOF[J]. Thermal power generation, 2010, 39(8): 12-17.
MA Shuangchen, JIN Xin, SUN Yunxue, et al. THE FORMATION MECHANISM OF AMMONIUM BISULFATE IN SCR FLUE GAS DENITRIFICATION PROCESS AND CONTROL THEREOF[J]. Thermal power generation, 2010, 39(8): 12-17.DOI:
The principle of selective catalystic reduction(SCR) denitrification process has been briefly expounded
pointing out the harmfulness of ammonium bisulfate(ABS) occurred in SCR denitrification process.The main affecting factors for ABS formation
such as the mole ratio of NH3/NOx
the SO3 concetration
and the dew point of ABS etc.
have been analysed in detail.According to the properties of ABS
the measures for controlling formation of ABS and recducing negative impacts of ABS have been put forward:through controlling the amount of ammonia escape in the SCR process and the oxidation rate of SO2 in the flue gas
the formation amount of ABS is to be reduced;in order to prevent the catalyst to lose its activity due to hold-up of ABS
the operating time of SCR under low load has to be reasonably controlled;for effectively decreasing the formation rate of ABS on heat-exchanging elements in the preheater
the ceramic coating has to be selected for said elements.